(η6-Benzene)chlorido[2-(pyridin-2-yl)quinoline-κ2N,N′]ruthenium(II) tetrafluoridoborate
The title compound, [RuCl(C6H6)(C14H10N2)]BF4 or [Ru(η6-benzene)(L)Cl]+BF4− [where L denotes the 2-(pyridin-2-yl)quinoline ligand], crystallizes in the monoclinic space group P21/c. The coordination environment around RuII is best described as pseudo-octahedral, resembling the familiar half-sandwich...
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International Union of Crystallography
2025-01-01
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| Online Access: | https://journals.iucr.org/paper?S2414314624012409 |
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| author | Manikandan Varadhan Ibanpynhunlang Passi Thangaraja Chinnathangavel Venugopal Rajendiran |
| author_facet | Manikandan Varadhan Ibanpynhunlang Passi Thangaraja Chinnathangavel Venugopal Rajendiran |
| author_sort | Manikandan Varadhan |
| collection | DOAJ |
| description | The title compound, [RuCl(C6H6)(C14H10N2)]BF4 or [Ru(η6-benzene)(L)Cl]+BF4− [where L denotes the 2-(pyridin-2-yl)quinoline ligand], crystallizes in the monoclinic space group P21/c. The coordination environment around RuII is best described as pseudo-octahedral, resembling the familiar half-sandwich ‘three-legged piano-stool’ shape. In the coordination sphere, the η6-binding benzene ligand coordinates with the central RuII atom occupying the ‘seat’ of the stool with a metal-to-centroid distance of 1.695 (17) Å, while the chelate ligand L coordinates with its N atoms and, together with the Cl ligand, defines the ‘legs’ of the stool. Apart from Coulombic forces, C—H...F and C—H...Cl hydrogen-bonding interactions consolidate the crystal packing. |
| format | Article |
| id | doaj-art-f748bd87066a4129b6a6b64bc6e40a49 |
| institution | Kabale University |
| issn | 2414-3146 |
| language | English |
| publishDate | 2025-01-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | IUCrData |
| spelling | doaj-art-f748bd87066a4129b6a6b64bc6e40a492025-02-06T07:26:56ZengInternational Union of CrystallographyIUCrData2414-31462025-01-01101x24124010.1107/S2414314624012409wm4225(η6-Benzene)chlorido[2-(pyridin-2-yl)quinoline-κ2N,N′]ruthenium(II) tetrafluoridoborateManikandan Varadhan0Ibanpynhunlang Passi1Thangaraja Chinnathangavel2Venugopal Rajendiran3Department of Chemistry, School of Basic and Applied Sciences, Central University of Tamil Nadu, Thiruvarur 610 005, IndiaDepartment of Chemistry, North Eastern Hill University, Shillong 793 022, IndiaDepartment of Chemistry, Anna University Regional Campus, Madurai 625 019, Tamil Nadu, IndiaDepartment of Chemistry, School of Basic and Applied Sciences, Central University of Tamil Nadu, Thiruvarur 610 005, IndiaThe title compound, [RuCl(C6H6)(C14H10N2)]BF4 or [Ru(η6-benzene)(L)Cl]+BF4− [where L denotes the 2-(pyridin-2-yl)quinoline ligand], crystallizes in the monoclinic space group P21/c. The coordination environment around RuII is best described as pseudo-octahedral, resembling the familiar half-sandwich ‘three-legged piano-stool’ shape. In the coordination sphere, the η6-binding benzene ligand coordinates with the central RuII atom occupying the ‘seat’ of the stool with a metal-to-centroid distance of 1.695 (17) Å, while the chelate ligand L coordinates with its N atoms and, together with the Cl ligand, defines the ‘legs’ of the stool. Apart from Coulombic forces, C—H...F and C—H...Cl hydrogen-bonding interactions consolidate the crystal packing.https://journals.iucr.org/paper?S2414314624012409ruthenium(ii)2-(pyridin-2-yl)quinolineη6-benzenecrystal structure |
| spellingShingle | Manikandan Varadhan Ibanpynhunlang Passi Thangaraja Chinnathangavel Venugopal Rajendiran (η6-Benzene)chlorido[2-(pyridin-2-yl)quinoline-κ2N,N′]ruthenium(II) tetrafluoridoborate IUCrData ruthenium(ii) 2-(pyridin-2-yl)quinoline η6-benzene crystal structure |
| title | (η6-Benzene)chlorido[2-(pyridin-2-yl)quinoline-κ2N,N′]ruthenium(II) tetrafluoridoborate |
| title_full | (η6-Benzene)chlorido[2-(pyridin-2-yl)quinoline-κ2N,N′]ruthenium(II) tetrafluoridoborate |
| title_fullStr | (η6-Benzene)chlorido[2-(pyridin-2-yl)quinoline-κ2N,N′]ruthenium(II) tetrafluoridoborate |
| title_full_unstemmed | (η6-Benzene)chlorido[2-(pyridin-2-yl)quinoline-κ2N,N′]ruthenium(II) tetrafluoridoborate |
| title_short | (η6-Benzene)chlorido[2-(pyridin-2-yl)quinoline-κ2N,N′]ruthenium(II) tetrafluoridoborate |
| title_sort | η6 benzene chlorido 2 pyridin 2 yl quinoline κ2n n ruthenium ii tetrafluoridoborate |
| topic | ruthenium(ii) 2-(pyridin-2-yl)quinoline η6-benzene crystal structure |
| url | https://journals.iucr.org/paper?S2414314624012409 |
| work_keys_str_mv | AT manikandanvaradhan ē6benzenechlorido2pyridin2ylquinolinek2nnrutheniumiitetrafluoridoborate AT ibanpynhunlangpassi ē6benzenechlorido2pyridin2ylquinolinek2nnrutheniumiitetrafluoridoborate AT thangarajachinnathangavel ē6benzenechlorido2pyridin2ylquinolinek2nnrutheniumiitetrafluoridoborate AT venugopalrajendiran ē6benzenechlorido2pyridin2ylquinolinek2nnrutheniumiitetrafluoridoborate |