Knoevenagel Condensation of Aldehydes with Ethyl Cyanoacetate in Water Catalyzed by P4VP/Al2O3-SiO2

This paper reports the preparation and characterization of poly(4-vinylpyridine) (P4VP) supported on Al2O3-SiO2 and its application for Knoevenagel condensation reaction of various aldehydes with ethyl cyanoacetate in water as a green solvent. The results illustrate that the sample containing 0.6 mo...

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Main Authors: Majid Kolahdoozan, Roozbeh Javad Kalbasi, Zohreh S. Shahzeidi, Farzad Zamani
Format: Article
Language:English
Published: Wiley 2013-01-01
Series:Journal of Chemistry
Online Access:http://dx.doi.org/10.1155/2013/496837
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author Majid Kolahdoozan
Roozbeh Javad Kalbasi
Zohreh S. Shahzeidi
Farzad Zamani
author_facet Majid Kolahdoozan
Roozbeh Javad Kalbasi
Zohreh S. Shahzeidi
Farzad Zamani
author_sort Majid Kolahdoozan
collection DOAJ
description This paper reports the preparation and characterization of poly(4-vinylpyridine) (P4VP) supported on Al2O3-SiO2 and its application for Knoevenagel condensation reaction of various aldehydes with ethyl cyanoacetate in water as a green solvent. The results illustrate that the sample containing 0.6 molar ratio of Al to Si exhibits the highest yield (98%) in the reaction of benzaldehyde with ethyl cyanoacetate with 100% selectivity to the arylidene derivative.
format Article
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institution Kabale University
issn 2090-9063
2090-9071
language English
publishDate 2013-01-01
publisher Wiley
record_format Article
series Journal of Chemistry
spelling doaj-art-f5e5b7594e7942c7a1de560dc676457b2025-02-03T06:12:10ZengWileyJournal of Chemistry2090-90632090-90712013-01-01201310.1155/2013/496837496837Knoevenagel Condensation of Aldehydes with Ethyl Cyanoacetate in Water Catalyzed by P4VP/Al2O3-SiO2Majid Kolahdoozan0Roozbeh Javad Kalbasi1Zohreh S. Shahzeidi2Farzad Zamani3Department of Chemistry, Shahreza Branch, Islamic Azad University, Isfahan, Shahreza 311-86145, IranDepartment of Chemistry, Shahreza Branch, Islamic Azad University, Isfahan, Shahreza 311-86145, IranDepartment of Chemistry, Shahreza Branch, Islamic Azad University, Isfahan, Shahreza 311-86145, IranDepartment of Chemistry, Shahreza Branch, Islamic Azad University, Isfahan, Shahreza 311-86145, IranThis paper reports the preparation and characterization of poly(4-vinylpyridine) (P4VP) supported on Al2O3-SiO2 and its application for Knoevenagel condensation reaction of various aldehydes with ethyl cyanoacetate in water as a green solvent. The results illustrate that the sample containing 0.6 molar ratio of Al to Si exhibits the highest yield (98%) in the reaction of benzaldehyde with ethyl cyanoacetate with 100% selectivity to the arylidene derivative.http://dx.doi.org/10.1155/2013/496837
spellingShingle Majid Kolahdoozan
Roozbeh Javad Kalbasi
Zohreh S. Shahzeidi
Farzad Zamani
Knoevenagel Condensation of Aldehydes with Ethyl Cyanoacetate in Water Catalyzed by P4VP/Al2O3-SiO2
Journal of Chemistry
title Knoevenagel Condensation of Aldehydes with Ethyl Cyanoacetate in Water Catalyzed by P4VP/Al2O3-SiO2
title_full Knoevenagel Condensation of Aldehydes with Ethyl Cyanoacetate in Water Catalyzed by P4VP/Al2O3-SiO2
title_fullStr Knoevenagel Condensation of Aldehydes with Ethyl Cyanoacetate in Water Catalyzed by P4VP/Al2O3-SiO2
title_full_unstemmed Knoevenagel Condensation of Aldehydes with Ethyl Cyanoacetate in Water Catalyzed by P4VP/Al2O3-SiO2
title_short Knoevenagel Condensation of Aldehydes with Ethyl Cyanoacetate in Water Catalyzed by P4VP/Al2O3-SiO2
title_sort knoevenagel condensation of aldehydes with ethyl cyanoacetate in water catalyzed by p4vp al2o3 sio2
url http://dx.doi.org/10.1155/2013/496837
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