Synthesis of Hyperbranched Polymer Using Slow Monomer Addition Method
This paper details the synthesis of a well-defined hyperbranched polymer using a slow monomer addition method. The polymerization under slow monomer addition conditions results in a very low monomer concentration actually present in the reaction mixture, and the exclusive reaction of the monomer wit...
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Format: | Article |
Language: | English |
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Wiley
2012-01-01
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Series: | International Journal of Polymer Science |
Online Access: | http://dx.doi.org/10.1155/2012/816163 |
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author | Toshifumi Satoh |
author_facet | Toshifumi Satoh |
author_sort | Toshifumi Satoh |
collection | DOAJ |
description | This paper details the synthesis of a well-defined hyperbranched polymer using a slow monomer addition method. The polymerization under slow monomer addition conditions results in a very low monomer concentration actually present in the reaction mixture, and the exclusive reaction of the monomer with the growing polyfunctional macromolecules occurs, resulting in a high molecular weight and a high degree of branching value. Thus, the slow monomer addition is a versatile and preferential method for the controlled synthesis of a well-defined hyperbranched polymer with both a high molecular weight and a high degree of branching value. |
format | Article |
id | doaj-art-f53d9de1163d4468b274d06554661baa |
institution | Kabale University |
issn | 1687-9422 1687-9430 |
language | English |
publishDate | 2012-01-01 |
publisher | Wiley |
record_format | Article |
series | International Journal of Polymer Science |
spelling | doaj-art-f53d9de1163d4468b274d06554661baa2025-02-03T01:11:36ZengWileyInternational Journal of Polymer Science1687-94221687-94302012-01-01201210.1155/2012/816163816163Synthesis of Hyperbranched Polymer Using Slow Monomer Addition MethodToshifumi Satoh0Division of Biotechnology and Macromolecular Chemistry, Faculty of Engineering, Hokkaido University, Sapporo 060-8628, JapanThis paper details the synthesis of a well-defined hyperbranched polymer using a slow monomer addition method. The polymerization under slow monomer addition conditions results in a very low monomer concentration actually present in the reaction mixture, and the exclusive reaction of the monomer with the growing polyfunctional macromolecules occurs, resulting in a high molecular weight and a high degree of branching value. Thus, the slow monomer addition is a versatile and preferential method for the controlled synthesis of a well-defined hyperbranched polymer with both a high molecular weight and a high degree of branching value.http://dx.doi.org/10.1155/2012/816163 |
spellingShingle | Toshifumi Satoh Synthesis of Hyperbranched Polymer Using Slow Monomer Addition Method International Journal of Polymer Science |
title | Synthesis of Hyperbranched Polymer Using Slow Monomer Addition Method |
title_full | Synthesis of Hyperbranched Polymer Using Slow Monomer Addition Method |
title_fullStr | Synthesis of Hyperbranched Polymer Using Slow Monomer Addition Method |
title_full_unstemmed | Synthesis of Hyperbranched Polymer Using Slow Monomer Addition Method |
title_short | Synthesis of Hyperbranched Polymer Using Slow Monomer Addition Method |
title_sort | synthesis of hyperbranched polymer using slow monomer addition method |
url | http://dx.doi.org/10.1155/2012/816163 |
work_keys_str_mv | AT toshifumisatoh synthesisofhyperbranchedpolymerusingslowmonomeradditionmethod |