Boosted Thermal Storage Performance of LiOH·H2O by Carbon Nanotubes Isolated Multilayered Graphene Oxide Frames

Cellulose-originated three-dimensional graphene oxide CNT-modified LiOH·H2O (3D-GO-CNTs-LiOH·H2O) was synthesized by the hydrothermal method. LiOH·H2O nanoparticles (5–50 nm) were homogeneously dispersed inside the 3D-GO-CNTs frames. The composite showed enhanced heat storage density, excellent ther...

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Main Authors: Yuxian Wang, Jing Gu, Xian Li, Yan Zhu, Hongyun Hu, Huan Liu, Guangqian Luo, Hong Yao
Format: Article
Language:English
Published: Wiley 2022-01-01
Series:Advances in Materials Science and Engineering
Online Access:http://dx.doi.org/10.1155/2022/3109178
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author Yuxian Wang
Jing Gu
Xian Li
Yan Zhu
Hongyun Hu
Huan Liu
Guangqian Luo
Hong Yao
author_facet Yuxian Wang
Jing Gu
Xian Li
Yan Zhu
Hongyun Hu
Huan Liu
Guangqian Luo
Hong Yao
author_sort Yuxian Wang
collection DOAJ
description Cellulose-originated three-dimensional graphene oxide CNT-modified LiOH·H2O (3D-GO-CNTs-LiOH·H2O) was synthesized by the hydrothermal method. LiOH·H2O nanoparticles (5–50 nm) were homogeneously dispersed inside the 3D-GO-CNTs frames. The composite showed enhanced heat storage density, excellent thermal conductivity, and greatly improved hydration rate due to both the hydrophilic reaction interface of 3D-GO-CNTs frames and reduced size of LiOH·H2O nanoparticles. LiOH·H2O content ratio of 23% (3D-GO-CNTs-LiOH·H2O-1) results in best heat storage performance with activation energy of 23.8 kJ/mol, thermal conductivity of 3.06 W/m·K, and heat storage capacity of 2800 kJ/kg. 3D-GO-CNTs-LiOH·H2O shows 4.2 folders heat storage capacity than that of pristine LiOH·H2O after the same hydration reaction. Other composite materials also show good performance: 3D-GO-CNTs-LiOH·H2O-2 (activation energy: 28.5 kJ/mol, thermal conductivity: 2.33 W/m·K, and heat storage capacity: 2051 kJ/kg.); 3D-GO-CNTs-LiOH·H2O-3 (activation energy: 32.3 kJ/mol, thermal conductivity: 2.01 W/m·K, and heat storage capacity: 1983 kJ/kg.). The addition of cellulose originated 3D-GO-CNTs was proved to be an excellent strategy to boost the heat storage performance of LiOH·H2O.
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publisher Wiley
record_format Article
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spelling doaj-art-ed556a11dc19457fafa9ae8f043ab1442025-02-03T01:11:56ZengWileyAdvances in Materials Science and Engineering1687-84422022-01-01202210.1155/2022/3109178Boosted Thermal Storage Performance of LiOH·H2O by Carbon Nanotubes Isolated Multilayered Graphene Oxide FramesYuxian Wang0Jing Gu1Xian Li2Yan Zhu3Hongyun Hu4Huan Liu5Guangqian Luo6Hong Yao7State Key Laboratory of Coal CombustionGuangzhou Institute of Energy ConversionState Key Laboratory of Coal CombustionState Key Laboratory of Coal CombustionState Key Laboratory of Coal CombustionState Key Laboratory of Coal CombustionState Key Laboratory of Coal CombustionState Key Laboratory of Coal CombustionCellulose-originated three-dimensional graphene oxide CNT-modified LiOH·H2O (3D-GO-CNTs-LiOH·H2O) was synthesized by the hydrothermal method. LiOH·H2O nanoparticles (5–50 nm) were homogeneously dispersed inside the 3D-GO-CNTs frames. The composite showed enhanced heat storage density, excellent thermal conductivity, and greatly improved hydration rate due to both the hydrophilic reaction interface of 3D-GO-CNTs frames and reduced size of LiOH·H2O nanoparticles. LiOH·H2O content ratio of 23% (3D-GO-CNTs-LiOH·H2O-1) results in best heat storage performance with activation energy of 23.8 kJ/mol, thermal conductivity of 3.06 W/m·K, and heat storage capacity of 2800 kJ/kg. 3D-GO-CNTs-LiOH·H2O shows 4.2 folders heat storage capacity than that of pristine LiOH·H2O after the same hydration reaction. Other composite materials also show good performance: 3D-GO-CNTs-LiOH·H2O-2 (activation energy: 28.5 kJ/mol, thermal conductivity: 2.33 W/m·K, and heat storage capacity: 2051 kJ/kg.); 3D-GO-CNTs-LiOH·H2O-3 (activation energy: 32.3 kJ/mol, thermal conductivity: 2.01 W/m·K, and heat storage capacity: 1983 kJ/kg.). The addition of cellulose originated 3D-GO-CNTs was proved to be an excellent strategy to boost the heat storage performance of LiOH·H2O.http://dx.doi.org/10.1155/2022/3109178
spellingShingle Yuxian Wang
Jing Gu
Xian Li
Yan Zhu
Hongyun Hu
Huan Liu
Guangqian Luo
Hong Yao
Boosted Thermal Storage Performance of LiOH·H2O by Carbon Nanotubes Isolated Multilayered Graphene Oxide Frames
Advances in Materials Science and Engineering
title Boosted Thermal Storage Performance of LiOH·H2O by Carbon Nanotubes Isolated Multilayered Graphene Oxide Frames
title_full Boosted Thermal Storage Performance of LiOH·H2O by Carbon Nanotubes Isolated Multilayered Graphene Oxide Frames
title_fullStr Boosted Thermal Storage Performance of LiOH·H2O by Carbon Nanotubes Isolated Multilayered Graphene Oxide Frames
title_full_unstemmed Boosted Thermal Storage Performance of LiOH·H2O by Carbon Nanotubes Isolated Multilayered Graphene Oxide Frames
title_short Boosted Thermal Storage Performance of LiOH·H2O by Carbon Nanotubes Isolated Multilayered Graphene Oxide Frames
title_sort boosted thermal storage performance of lioh·h2o by carbon nanotubes isolated multilayered graphene oxide frames
url http://dx.doi.org/10.1155/2022/3109178
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