Thermodynamic description of phase equilibrium in systems MCl<sub>5</sub>–M<sup>’</sup>Cl<sub>5</sub>, (M = Nb, Ta, Mo, W, Re) and MCl<sub>3</sub>–M<sup>’</sup>Cl<sub>3</sub>, (M = Ln)

Thermodynamic description of phase equilibrium in systems MCl<sub>5</sub>–M<sup>’</sup>Cl<sub>5</sub>, (M = Nb, Ta, Mo, W, Re) and MCl<sub>3</sub>–M<sup>’</sup>Cl<sub>3</sub>, (M = Ln)

The paper considers the Saint-John-Bloch model and proves that this model is applicable for describing phase equilibrium in binary systems formed by pentachlorides of d-elements of groups V, Vl, Vll of the periodic system and lanthanide chlorides. The dependence of the possibility of forming solid s...

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Bibliographic Details
Main Authors: A. V. Galantsev, D. V. Drobot, L. V. Yanshina
Format: Article
Language:Russian
Published: MIREA - Russian Technological University 2011-02-01
Series:Тонкие химические технологии
Subjects:
saint-john-bloch diagram
binary systems
phase equilibrium
lanthanides
Online Access:https://www.finechem-mirea.ru/jour/article/view/886
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