CuO-Loaded Macroreticular Anion Exchange Hybrid Polymers Obtained via Tetrachlorocuprate(II) Ionic Form
Amberlite IRA900 Cl, the macroreticular, polystyrene/divinylbenzene anion exchanger containing quaternary ammonium groups, was used as the support for copper(II) oxide deposition, and, as a result a new hybrid ion exchanger (HIX) was obtained. The CuO deposit was introduced into the anion exchanger...
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| Format: | Article |
| Language: | English |
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Wiley
2017-01-01
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| Series: | International Journal of Polymer Science |
| Online Access: | http://dx.doi.org/10.1155/2017/4574397 |
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| author | Elżbieta Kociołek-Balawejder Ewa Stanisławska Irena Jacukowicz-Sobala Daniel Ociński |
| author_facet | Elżbieta Kociołek-Balawejder Ewa Stanisławska Irena Jacukowicz-Sobala Daniel Ociński |
| author_sort | Elżbieta Kociołek-Balawejder |
| collection | DOAJ |
| description | Amberlite IRA900 Cl, the macroreticular, polystyrene/divinylbenzene anion exchanger containing quaternary ammonium groups, was used as the support for copper(II) oxide deposition, and, as a result a new hybrid ion exchanger (HIX) was obtained. The CuO deposit was introduced into the anion exchanger structure in two steps conducted batchwise at ambient temperature. First, the functional groups were transformed from the Cl- into the CuCl42- form, using 5 mol dm−3 NaCl or HCl solution with CuCl2 being added, and then the intermediate product was contacted with NaOH/NaCl solution to precipitate CuO within the polymer beads. A HIX containing as much as 11.5% Cu was obtained. The distribution of the inorganic load within the porous matrix of polymer beads was atypical; CuO was mainly deposited in the outer parts of the beads and only a small amount was in their inner parts. This may be advantageous in some practical applications concerning the removal of harmful admixtures from waters in sorption processes. |
| format | Article |
| id | doaj-art-e072ffdff2744b92b497eb83b720a82c |
| institution | Kabale University |
| issn | 1687-9422 1687-9430 |
| language | English |
| publishDate | 2017-01-01 |
| publisher | Wiley |
| record_format | Article |
| series | International Journal of Polymer Science |
| spelling | doaj-art-e072ffdff2744b92b497eb83b720a82c2025-02-03T01:23:41ZengWileyInternational Journal of Polymer Science1687-94221687-94302017-01-01201710.1155/2017/45743974574397CuO-Loaded Macroreticular Anion Exchange Hybrid Polymers Obtained via Tetrachlorocuprate(II) Ionic FormElżbieta Kociołek-Balawejder0Ewa Stanisławska1Irena Jacukowicz-Sobala2Daniel Ociński3Department of Industrial Chemistry, Wrocław University of Economics, Ul. Komandorska 118/120, 53-345 Wrocław, PolandDepartment of Industrial Chemistry, Wrocław University of Economics, Ul. Komandorska 118/120, 53-345 Wrocław, PolandDepartment of Industrial Chemistry, Wrocław University of Economics, Ul. Komandorska 118/120, 53-345 Wrocław, PolandDepartment of Industrial Chemistry, Wrocław University of Economics, Ul. Komandorska 118/120, 53-345 Wrocław, PolandAmberlite IRA900 Cl, the macroreticular, polystyrene/divinylbenzene anion exchanger containing quaternary ammonium groups, was used as the support for copper(II) oxide deposition, and, as a result a new hybrid ion exchanger (HIX) was obtained. The CuO deposit was introduced into the anion exchanger structure in two steps conducted batchwise at ambient temperature. First, the functional groups were transformed from the Cl- into the CuCl42- form, using 5 mol dm−3 NaCl or HCl solution with CuCl2 being added, and then the intermediate product was contacted with NaOH/NaCl solution to precipitate CuO within the polymer beads. A HIX containing as much as 11.5% Cu was obtained. The distribution of the inorganic load within the porous matrix of polymer beads was atypical; CuO was mainly deposited in the outer parts of the beads and only a small amount was in their inner parts. This may be advantageous in some practical applications concerning the removal of harmful admixtures from waters in sorption processes.http://dx.doi.org/10.1155/2017/4574397 |
| spellingShingle | Elżbieta Kociołek-Balawejder Ewa Stanisławska Irena Jacukowicz-Sobala Daniel Ociński CuO-Loaded Macroreticular Anion Exchange Hybrid Polymers Obtained via Tetrachlorocuprate(II) Ionic Form International Journal of Polymer Science |
| title | CuO-Loaded Macroreticular Anion Exchange Hybrid Polymers Obtained via Tetrachlorocuprate(II) Ionic Form |
| title_full | CuO-Loaded Macroreticular Anion Exchange Hybrid Polymers Obtained via Tetrachlorocuprate(II) Ionic Form |
| title_fullStr | CuO-Loaded Macroreticular Anion Exchange Hybrid Polymers Obtained via Tetrachlorocuprate(II) Ionic Form |
| title_full_unstemmed | CuO-Loaded Macroreticular Anion Exchange Hybrid Polymers Obtained via Tetrachlorocuprate(II) Ionic Form |
| title_short | CuO-Loaded Macroreticular Anion Exchange Hybrid Polymers Obtained via Tetrachlorocuprate(II) Ionic Form |
| title_sort | cuo loaded macroreticular anion exchange hybrid polymers obtained via tetrachlorocuprate ii ionic form |
| url | http://dx.doi.org/10.1155/2017/4574397 |
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