Removal of Pb (II) Ions from Aqueous Solutions by Cladophora rivularis (Linnaeus) Hoek

Biosorption of Pb(II) using Cladophora rivularis was examined as a function of initial pH heavy metal concentration and temperature. The optimum pH value for the biosorption of lead was 4.0. The adsorption equilibriums were well described by Langmuir and Freundlich isotherm models and it was implied...

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Main Authors: Naser Jafari, Zoreh Senobari
Format: Article
Language:English
Published: Wiley 2012-01-01
Series:The Scientific World Journal
Online Access:http://dx.doi.org/10.1100/2012/793606
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author Naser Jafari
Zoreh Senobari
author_facet Naser Jafari
Zoreh Senobari
author_sort Naser Jafari
collection DOAJ
description Biosorption of Pb(II) using Cladophora rivularis was examined as a function of initial pH heavy metal concentration and temperature. The optimum pH value for the biosorption of lead was 4.0. The adsorption equilibriums were well described by Langmuir and Freundlich isotherm models and it was implied by the results that the C. rivularis biomass is suitable for the development of efficient biosorbent in order to remove Pb(II) from wastewater and to recover it. The high values of correlation coefficient (𝑅2=0.984) demonstrate equilibrium data concerning algal biomass, which is well fitted in Freundlich isotherms model equations. The dimensionless parameter RL is found in the range of 0.0639 to 0.1925 (0<𝑅𝐿<1), which confirms the favorable biosorption process. Fourier transform infra-red (FTIR) spectroscopy of C. rivularis was used to reveal the main function groups of biosorption, which were hydroxyl, amine groups, C–H stretching vibrations of –CH3 and –CH2, and complexation with functional groups. All these results suggest that C. rivularis can be used effectively for removal of Pb(II).
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spelling doaj-art-df4aef51e03a4f8c8cbb64ec393cc2802025-02-03T05:46:17ZengWileyThe Scientific World Journal1537-744X2012-01-01201210.1100/2012/793606793606Removal of Pb (II) Ions from Aqueous Solutions by Cladophora rivularis (Linnaeus) HoekNaser Jafari0Zoreh Senobari1Department of Biology, Faculty of Basic Sciences, University of Mazandaran, Babolsar 11252, IranDepartment of Biology, Faculty of Basic Sciences, University of Mazandaran, Babolsar 11252, IranBiosorption of Pb(II) using Cladophora rivularis was examined as a function of initial pH heavy metal concentration and temperature. The optimum pH value for the biosorption of lead was 4.0. The adsorption equilibriums were well described by Langmuir and Freundlich isotherm models and it was implied by the results that the C. rivularis biomass is suitable for the development of efficient biosorbent in order to remove Pb(II) from wastewater and to recover it. The high values of correlation coefficient (𝑅2=0.984) demonstrate equilibrium data concerning algal biomass, which is well fitted in Freundlich isotherms model equations. The dimensionless parameter RL is found in the range of 0.0639 to 0.1925 (0<𝑅𝐿<1), which confirms the favorable biosorption process. Fourier transform infra-red (FTIR) spectroscopy of C. rivularis was used to reveal the main function groups of biosorption, which were hydroxyl, amine groups, C–H stretching vibrations of –CH3 and –CH2, and complexation with functional groups. All these results suggest that C. rivularis can be used effectively for removal of Pb(II).http://dx.doi.org/10.1100/2012/793606
spellingShingle Naser Jafari
Zoreh Senobari
Removal of Pb (II) Ions from Aqueous Solutions by Cladophora rivularis (Linnaeus) Hoek
The Scientific World Journal
title Removal of Pb (II) Ions from Aqueous Solutions by Cladophora rivularis (Linnaeus) Hoek
title_full Removal of Pb (II) Ions from Aqueous Solutions by Cladophora rivularis (Linnaeus) Hoek
title_fullStr Removal of Pb (II) Ions from Aqueous Solutions by Cladophora rivularis (Linnaeus) Hoek
title_full_unstemmed Removal of Pb (II) Ions from Aqueous Solutions by Cladophora rivularis (Linnaeus) Hoek
title_short Removal of Pb (II) Ions from Aqueous Solutions by Cladophora rivularis (Linnaeus) Hoek
title_sort removal of pb ii ions from aqueous solutions by cladophora rivularis linnaeus hoek
url http://dx.doi.org/10.1100/2012/793606
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