Underlying Mechanisms of Chromatographic H/D, H/F, <i>cis/trans</i> and Isomerism Effects in GC-MS

Underlying Mechanisms of Chromatographic H/D, H/F, <i>cis/trans</i> and Isomerism Effects in GC-MS

Charge-free gaseous molecules labeled with deuterium <sup>2</sup>H (D) atoms elute earlier than their protium-analogs <sup>1</sup>H (H) from most stationary GC phases. This effect is known as the chromatographic H/D isotope effect (<i>hd</i>IE<sub>C</sub&...

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Bibliographic Details
Main Author: Dimitrios Tsikas
Format: Article
Language:English
Published: MDPI AG 2025-01-01
Series:Metabolites
Subjects:
<i>cis/trans</i>-effect
gas chromatography
H/D-effect
H/F-effect
mass spectrometry
mechanism
Online Access:https://www.mdpi.com/2218-1989/15/1/43
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