Inter- und intramolekulare Abfangreaktionen photochemisch erzeugter Diarylnitrilimine

Photolysis of 2,5-diphenyltetrazoIe (2a) in an ether/pentane/ ethanol-glass at 77K in the presence of a 10fold excess of propionic acid yields diphenylnitrilimine (1b). Warming up the solution to 130K leads to the formation of the ethanol adduct 5 (scheme 1 and fig. 1). Irradiation of 2a and propio...

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Bibliographic Details
Main Authors: Hansruedi Meier, Willy Heinzelmann, Heinz Heimgartner
Format: Article
Language:deu
Published: Swiss Chemical Society 1980-12-01
Series:CHIMIA
Online Access:https://www.chimia.ch/chimia/article/view/9496
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