Ultrasonic Studies of Some Biomolecules in Aqueous Guanidine Hydrochloride Solutions at 298.15 K
Ultrasonic velocity (U), viscocity (η) and density (ρ) of L - ascorbic acid, dextrose and sucrose in aqueous guanidine hydrochloride (0.3 m) have been measured at 298.15 K. The derived acoustical parameters namely adiabatic compressibility (β), apparent molal compressibility (ΨK) apparent molal volu...
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2011-01-01
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Series: | E-Journal of Chemistry |
Online Access: | http://dx.doi.org/10.1155/2011/856284 |
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author | R. Palani A. Geetha S. V. S. L. Poornima |
author_facet | R. Palani A. Geetha S. V. S. L. Poornima |
author_sort | R. Palani |
collection | DOAJ |
description | Ultrasonic velocity (U), viscocity (η) and density (ρ) of L - ascorbic acid, dextrose and sucrose in aqueous guanidine hydrochloride (0.3 m) have been measured at 298.15 K. The derived acoustical parameters namely adiabatic compressibility (β), apparent molal compressibility (ΨK) apparent molal volume (ΨV) limiting apparent molal compressibility (Ψ0K) limiting apparent molal volume (Ψ0V) and their constants (SK, Sv) and viscosity B- coefficient and hydration number (nH) have been computed from the experimental data. The variation of these parameters with respect to the molality of solutes have been explained on the basis of solute-solvent interaction and structure making tendency of the solutes in solvents. |
format | Article |
id | doaj-art-db28a9f4bbc34bc5a09d9a4c06e62d8b |
institution | Kabale University |
issn | 0973-4945 2090-9810 |
language | English |
publishDate | 2011-01-01 |
publisher | Wiley |
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series | E-Journal of Chemistry |
spelling | doaj-art-db28a9f4bbc34bc5a09d9a4c06e62d8b2025-02-03T01:22:12ZengWileyE-Journal of Chemistry0973-49452090-98102011-01-01831146115110.1155/2011/856284Ultrasonic Studies of Some Biomolecules in Aqueous Guanidine Hydrochloride Solutions at 298.15 KR. Palani0A. Geetha1S. V. S. L. Poornima2Department of Physics, D.D.E, Annamalai University, Annamalainagar 608 002, Tamil Nadu, IndiaDepartment of Physics, SRM University, Kattankulathur, Kancheepuram, 603203, IndiaDepartment of Physics, D.D.E, Annamalai University, Annamalainagar 608 002, Tamil Nadu, IndiaUltrasonic velocity (U), viscocity (η) and density (ρ) of L - ascorbic acid, dextrose and sucrose in aqueous guanidine hydrochloride (0.3 m) have been measured at 298.15 K. The derived acoustical parameters namely adiabatic compressibility (β), apparent molal compressibility (ΨK) apparent molal volume (ΨV) limiting apparent molal compressibility (Ψ0K) limiting apparent molal volume (Ψ0V) and their constants (SK, Sv) and viscosity B- coefficient and hydration number (nH) have been computed from the experimental data. The variation of these parameters with respect to the molality of solutes have been explained on the basis of solute-solvent interaction and structure making tendency of the solutes in solvents.http://dx.doi.org/10.1155/2011/856284 |
spellingShingle | R. Palani A. Geetha S. V. S. L. Poornima Ultrasonic Studies of Some Biomolecules in Aqueous Guanidine Hydrochloride Solutions at 298.15 K E-Journal of Chemistry |
title | Ultrasonic Studies of Some Biomolecules in Aqueous Guanidine Hydrochloride Solutions at 298.15 K |
title_full | Ultrasonic Studies of Some Biomolecules in Aqueous Guanidine Hydrochloride Solutions at 298.15 K |
title_fullStr | Ultrasonic Studies of Some Biomolecules in Aqueous Guanidine Hydrochloride Solutions at 298.15 K |
title_full_unstemmed | Ultrasonic Studies of Some Biomolecules in Aqueous Guanidine Hydrochloride Solutions at 298.15 K |
title_short | Ultrasonic Studies of Some Biomolecules in Aqueous Guanidine Hydrochloride Solutions at 298.15 K |
title_sort | ultrasonic studies of some biomolecules in aqueous guanidine hydrochloride solutions at 298 15 k |
url | http://dx.doi.org/10.1155/2011/856284 |
work_keys_str_mv | AT rpalani ultrasonicstudiesofsomebiomoleculesinaqueousguanidinehydrochloridesolutionsat29815k AT ageetha ultrasonicstudiesofsomebiomoleculesinaqueousguanidinehydrochloridesolutionsat29815k AT svslpoornima ultrasonicstudiesofsomebiomoleculesinaqueousguanidinehydrochloridesolutionsat29815k |