Ultrasonic Studies of Some Biomolecules in Aqueous Guanidine Hydrochloride Solutions at 298.15 K

Ultrasonic velocity (U), viscocity (η) and density (ρ) of L - ascorbic acid, dextrose and sucrose in aqueous guanidine hydrochloride (0.3 m) have been measured at 298.15 K. The derived acoustical parameters namely adiabatic compressibility (β), apparent molal compressibility (ΨK) apparent molal volu...

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Main Authors: R. Palani, A. Geetha, S. V. S. L. Poornima
Format: Article
Language:English
Published: Wiley 2011-01-01
Series:E-Journal of Chemistry
Online Access:http://dx.doi.org/10.1155/2011/856284
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author R. Palani
A. Geetha
S. V. S. L. Poornima
author_facet R. Palani
A. Geetha
S. V. S. L. Poornima
author_sort R. Palani
collection DOAJ
description Ultrasonic velocity (U), viscocity (η) and density (ρ) of L - ascorbic acid, dextrose and sucrose in aqueous guanidine hydrochloride (0.3 m) have been measured at 298.15 K. The derived acoustical parameters namely adiabatic compressibility (β), apparent molal compressibility (ΨK) apparent molal volume (ΨV) limiting apparent molal compressibility (Ψ0K) limiting apparent molal volume (Ψ0V) and their constants (SK, Sv) and viscosity B- coefficient and hydration number (nH) have been computed from the experimental data. The variation of these parameters with respect to the molality of solutes have been explained on the basis of solute-solvent interaction and structure making tendency of the solutes in solvents.
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spelling doaj-art-db28a9f4bbc34bc5a09d9a4c06e62d8b2025-02-03T01:22:12ZengWileyE-Journal of Chemistry0973-49452090-98102011-01-01831146115110.1155/2011/856284Ultrasonic Studies of Some Biomolecules in Aqueous Guanidine Hydrochloride Solutions at 298.15 KR. Palani0A. Geetha1S. V. S. L. Poornima2Department of Physics, D.D.E, Annamalai University, Annamalainagar 608 002, Tamil Nadu, IndiaDepartment of Physics, SRM University, Kattankulathur, Kancheepuram, 603203, IndiaDepartment of Physics, D.D.E, Annamalai University, Annamalainagar 608 002, Tamil Nadu, IndiaUltrasonic velocity (U), viscocity (η) and density (ρ) of L - ascorbic acid, dextrose and sucrose in aqueous guanidine hydrochloride (0.3 m) have been measured at 298.15 K. The derived acoustical parameters namely adiabatic compressibility (β), apparent molal compressibility (ΨK) apparent molal volume (ΨV) limiting apparent molal compressibility (Ψ0K) limiting apparent molal volume (Ψ0V) and their constants (SK, Sv) and viscosity B- coefficient and hydration number (nH) have been computed from the experimental data. The variation of these parameters with respect to the molality of solutes have been explained on the basis of solute-solvent interaction and structure making tendency of the solutes in solvents.http://dx.doi.org/10.1155/2011/856284
spellingShingle R. Palani
A. Geetha
S. V. S. L. Poornima
Ultrasonic Studies of Some Biomolecules in Aqueous Guanidine Hydrochloride Solutions at 298.15 K
E-Journal of Chemistry
title Ultrasonic Studies of Some Biomolecules in Aqueous Guanidine Hydrochloride Solutions at 298.15 K
title_full Ultrasonic Studies of Some Biomolecules in Aqueous Guanidine Hydrochloride Solutions at 298.15 K
title_fullStr Ultrasonic Studies of Some Biomolecules in Aqueous Guanidine Hydrochloride Solutions at 298.15 K
title_full_unstemmed Ultrasonic Studies of Some Biomolecules in Aqueous Guanidine Hydrochloride Solutions at 298.15 K
title_short Ultrasonic Studies of Some Biomolecules in Aqueous Guanidine Hydrochloride Solutions at 298.15 K
title_sort ultrasonic studies of some biomolecules in aqueous guanidine hydrochloride solutions at 298 15 k
url http://dx.doi.org/10.1155/2011/856284
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