Carbon Nanotubes: Synthesis via Chemical Vapour Deposition without Hydrogen, Surface Modification, and Application

The present study describes the growth of carbon nanotubes (CNTs) from liquefied petroleum gas (LPG) on an Fe2O3/Al2O3 precatalyst via a chemical vapour deposition (CVD) process without hydrogen. The obtained multiwalled CNTs exhibit a less-defective structure with an identical external diameter of...

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Main Authors: Nguyen Duc Vu Quyen, Dinh Quang Khieu, Tran Ngoc Tuyen, Dang Xuan Tin, Bui Thi Hoang Diem
Format: Article
Language:English
Published: Wiley 2019-01-01
Series:Journal of Chemistry
Online Access:http://dx.doi.org/10.1155/2019/4260153
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author Nguyen Duc Vu Quyen
Dinh Quang Khieu
Tran Ngoc Tuyen
Dang Xuan Tin
Bui Thi Hoang Diem
author_facet Nguyen Duc Vu Quyen
Dinh Quang Khieu
Tran Ngoc Tuyen
Dang Xuan Tin
Bui Thi Hoang Diem
author_sort Nguyen Duc Vu Quyen
collection DOAJ
description The present study describes the growth of carbon nanotubes (CNTs) from liquefied petroleum gas (LPG) on an Fe2O3/Al2O3 precatalyst via a chemical vapour deposition (CVD) process without hydrogen. The obtained multiwalled CNTs exhibit a less-defective structure with an identical external diameter of tubes of around 50 nm. The growth mechanism of CNTs suggests that the Fe2O3/Al2O3 precatalyst is reduced to Fe/Al2O3 during the synthesis process using the products of LPG decomposition, and the tip-growth mechanism is suggested. The resulting CNTs are surface-modified with potassium permanganate in the acid medium and used as an adsorbent for copper from aqueous solutions. The Langmuir and Freundlich isotherm models are employed to evaluate the adsorption data, and the maximum adsorption capacity of Cu(II) is 163.7 mg·g−1.
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id doaj-art-d8db69fe4e284d799e9b6b0b7bb4d388
institution Kabale University
issn 2090-9063
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language English
publishDate 2019-01-01
publisher Wiley
record_format Article
series Journal of Chemistry
spelling doaj-art-d8db69fe4e284d799e9b6b0b7bb4d3882025-02-03T07:23:47ZengWileyJournal of Chemistry2090-90632090-90712019-01-01201910.1155/2019/42601534260153Carbon Nanotubes: Synthesis via Chemical Vapour Deposition without Hydrogen, Surface Modification, and ApplicationNguyen Duc Vu Quyen0Dinh Quang Khieu1Tran Ngoc Tuyen2Dang Xuan Tin3Bui Thi Hoang Diem4Department of Chemistry, University of Sciences, Hue University, 77 Nguyen Hue Str., Hue, VietnamDepartment of Chemistry, University of Sciences, Hue University, 77 Nguyen Hue Str., Hue, VietnamDepartment of Chemistry, University of Sciences, Hue University, 77 Nguyen Hue Str., Hue, VietnamDepartment of Chemistry, University of Sciences, Hue University, 77 Nguyen Hue Str., Hue, VietnamDepartment of Chemistry, University of Sciences, Hue University, 77 Nguyen Hue Str., Hue, VietnamThe present study describes the growth of carbon nanotubes (CNTs) from liquefied petroleum gas (LPG) on an Fe2O3/Al2O3 precatalyst via a chemical vapour deposition (CVD) process without hydrogen. The obtained multiwalled CNTs exhibit a less-defective structure with an identical external diameter of tubes of around 50 nm. The growth mechanism of CNTs suggests that the Fe2O3/Al2O3 precatalyst is reduced to Fe/Al2O3 during the synthesis process using the products of LPG decomposition, and the tip-growth mechanism is suggested. The resulting CNTs are surface-modified with potassium permanganate in the acid medium and used as an adsorbent for copper from aqueous solutions. The Langmuir and Freundlich isotherm models are employed to evaluate the adsorption data, and the maximum adsorption capacity of Cu(II) is 163.7 mg·g−1.http://dx.doi.org/10.1155/2019/4260153
spellingShingle Nguyen Duc Vu Quyen
Dinh Quang Khieu
Tran Ngoc Tuyen
Dang Xuan Tin
Bui Thi Hoang Diem
Carbon Nanotubes: Synthesis via Chemical Vapour Deposition without Hydrogen, Surface Modification, and Application
Journal of Chemistry
title Carbon Nanotubes: Synthesis via Chemical Vapour Deposition without Hydrogen, Surface Modification, and Application
title_full Carbon Nanotubes: Synthesis via Chemical Vapour Deposition without Hydrogen, Surface Modification, and Application
title_fullStr Carbon Nanotubes: Synthesis via Chemical Vapour Deposition without Hydrogen, Surface Modification, and Application
title_full_unstemmed Carbon Nanotubes: Synthesis via Chemical Vapour Deposition without Hydrogen, Surface Modification, and Application
title_short Carbon Nanotubes: Synthesis via Chemical Vapour Deposition without Hydrogen, Surface Modification, and Application
title_sort carbon nanotubes synthesis via chemical vapour deposition without hydrogen surface modification and application
url http://dx.doi.org/10.1155/2019/4260153
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