Fast and Versatile Pathway in Fabrication of Polyelectrolyte Multilayer Nanofiltration Membrane with Tunable Properties

Thin film composite nanofiltration (NF) membranes are relatively new membranes compared to other types of pressure-driven membranes. However, they attract interest from researchers due to their versatility to be used in various applications. In this work, a new class of NF membrane was successfully...

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Main Author: Ahmad M. Alghamdi
Format: Article
Language:English
Published: Wiley 2021-01-01
Series:Journal of Chemistry
Online Access:http://dx.doi.org/10.1155/2021/9978596
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author Ahmad M. Alghamdi
author_facet Ahmad M. Alghamdi
author_sort Ahmad M. Alghamdi
collection DOAJ
description Thin film composite nanofiltration (NF) membranes are relatively new membranes compared to other types of pressure-driven membranes. However, they attract interest from researchers due to their versatility to be used in various applications. In this work, a new class of NF membrane was successfully fabricated through spin-assisted layer-by-layer assembly by depositing alternate layers of branched polyethylenimine (PEI) and poly(sodium 4-styrenesulfonate) (PSS) on ultrafiltration polysulfone (PSF) membrane. The suitability of the fabricated membranes for removal of divalent ions was investigated. It was found that the membrane consisting of (PEI/PSS)10–0.05 M NaCl showed MgCl2 rejection rate of 93.95% and permeation flux of 0.9 L/m2·h bar during tests performed using a crossflow permeation cell at a crossflow velocity of 0.65 m/s, MgCl2 feed concentration of 6530 ppm, pressure of 10 bar, temperature of 32.5°C, and pH of 6.5. This result suggests that this new fabrication method is suitable for producing polyelectrolyte multilayered (PEM) NF membranes that exhibit comparable membrane performance to commercial ones.
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spelling doaj-art-d89929d0d59e4d41a506fc08b4b3176a2025-02-03T05:43:47ZengWileyJournal of Chemistry2090-90632090-90712021-01-01202110.1155/2021/99785969978596Fast and Versatile Pathway in Fabrication of Polyelectrolyte Multilayer Nanofiltration Membrane with Tunable PropertiesAhmad M. Alghamdi0Chemical Engineering Department, Imam Mohammad Ibn Saud Islamic University, Riyadh 11432, Saudi ArabiaThin film composite nanofiltration (NF) membranes are relatively new membranes compared to other types of pressure-driven membranes. However, they attract interest from researchers due to their versatility to be used in various applications. In this work, a new class of NF membrane was successfully fabricated through spin-assisted layer-by-layer assembly by depositing alternate layers of branched polyethylenimine (PEI) and poly(sodium 4-styrenesulfonate) (PSS) on ultrafiltration polysulfone (PSF) membrane. The suitability of the fabricated membranes for removal of divalent ions was investigated. It was found that the membrane consisting of (PEI/PSS)10–0.05 M NaCl showed MgCl2 rejection rate of 93.95% and permeation flux of 0.9 L/m2·h bar during tests performed using a crossflow permeation cell at a crossflow velocity of 0.65 m/s, MgCl2 feed concentration of 6530 ppm, pressure of 10 bar, temperature of 32.5°C, and pH of 6.5. This result suggests that this new fabrication method is suitable for producing polyelectrolyte multilayered (PEM) NF membranes that exhibit comparable membrane performance to commercial ones.http://dx.doi.org/10.1155/2021/9978596
spellingShingle Ahmad M. Alghamdi
Fast and Versatile Pathway in Fabrication of Polyelectrolyte Multilayer Nanofiltration Membrane with Tunable Properties
Journal of Chemistry
title Fast and Versatile Pathway in Fabrication of Polyelectrolyte Multilayer Nanofiltration Membrane with Tunable Properties
title_full Fast and Versatile Pathway in Fabrication of Polyelectrolyte Multilayer Nanofiltration Membrane with Tunable Properties
title_fullStr Fast and Versatile Pathway in Fabrication of Polyelectrolyte Multilayer Nanofiltration Membrane with Tunable Properties
title_full_unstemmed Fast and Versatile Pathway in Fabrication of Polyelectrolyte Multilayer Nanofiltration Membrane with Tunable Properties
title_short Fast and Versatile Pathway in Fabrication of Polyelectrolyte Multilayer Nanofiltration Membrane with Tunable Properties
title_sort fast and versatile pathway in fabrication of polyelectrolyte multilayer nanofiltration membrane with tunable properties
url http://dx.doi.org/10.1155/2021/9978596
work_keys_str_mv AT ahmadmalghamdi fastandversatilepathwayinfabricationofpolyelectrolytemultilayernanofiltrationmembranewithtunableproperties