Formation on quartz substrate and study of properties of nanostructured layers from polyvinylen obtained by dehydrochlorination of polyvinyl chloride with modifying additive — iron nitrate
The work is devoted to solving the urgent task of developing simple ways of applying nanostructured layers of polymers to different substrates with a pairing system with properties of organic semiconductors. To obtain such polymers used dehydrochlorination of polyvinyl chloride under the influen...
Saved in:
| Main Authors: | , , , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
Omsk State Technical University, Federal State Autonoumos Educational Institution of Higher Education
2019-12-01
|
| Series: | Омский научный вестник |
| Subjects: | |
| Online Access: | https://www.omgtu.ru/general_information/media_omgtu/journal_of_omsk_research_journal/files/arhiv/2019/6%20(168)/83-88%20%D0%9A%D1%80%D0%B8%D0%B2%D0%BE%D0%B7%D1%83%D0%B1%D0%BE%D0%B2%20%D0%9E.%20%D0%92.,%20%D0%9A%D1%80%D1%8F%D0%B6%D0%B5%D0%B2%20%D0%AE.%20%D0%93.,%20%D0%90%D0%BD%D0%B8%D0%BA%D0%B5%D0%B5%D0%B2%D0%B0%20%D0%98.%20%D0%92.%20%D0%B8%20%D0%B4%D1%80..pdf |
| Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
| _version_ | 1832573652694990848 |
|---|---|
| author | O. V. Krivozubov Yu. G. Kryazhev I. V. Anikeeva N. A. Davletkildeev D. V. Sokolov O. N. Semenova |
| author_facet | O. V. Krivozubov Yu. G. Kryazhev I. V. Anikeeva N. A. Davletkildeev D. V. Sokolov O. N. Semenova |
| author_sort | O. V. Krivozubov |
| collection | DOAJ |
| description | The work is devoted to solving the urgent task of developing
simple ways of applying nanostructured layers of polymers
to different substrates with a pairing system with properties
of organic semiconductors. To obtain such polymers used
dehydrochlorination of polyvinyl chloride under the influence of
anilin in the solution dimethylsulfoxide. Iron nitrate is used as a
metal-containing modifying supplement. The nanostructured layers
of polyvinylen (polymer with the system of conjugated double
bonds) are obtained by forming on the plates of monocrystalline
quartz by the Langmur-Blodgett. The ASM method shows that in
the absence of metal-containing additives, layers of polyvinylens
are formed thick ~100 nm. Metal addition leads to significant
changes in the morphology of the layers. There is a formation
of conglomerates of rounded particles measuring ~30…50 nm.
The iron content in these layers is 0,04 % atomic. The study of
ultraviolet spectrums shows that iron dopation causes a multiple
increase in optical density in the entire range of wavelengths
studied. The resulting data can be used to create an elemental
base of molecular electronics. |
| format | Article |
| id | doaj-art-d4e408e1ed1842b4b82b330311d9e7ed |
| institution | Kabale University |
| issn | 1813-8225 2541-7541 |
| language | English |
| publishDate | 2019-12-01 |
| publisher | Omsk State Technical University, Federal State Autonoumos Educational Institution of Higher Education |
| record_format | Article |
| series | Омский научный вестник |
| spelling | doaj-art-d4e408e1ed1842b4b82b330311d9e7ed2025-02-02T03:32:57ZengOmsk State Technical University, Federal State Autonoumos Educational Institution of Higher EducationОмский научный вестник1813-82252541-75412019-12-016 (168)838810.25206/1813-8225-2019-168-83-88Formation on quartz substrate and study of properties of nanostructured layers from polyvinylen obtained by dehydrochlorination of polyvinyl chloride with modifying additive — iron nitrateO. V. Krivozubov0https://orcid.org/0000-0002-6439-4470Yu. G. Kryazhev1I. V. Anikeeva2https://orcid.org/0000-0002-9884-0600N. A. Davletkildeev3https://orcid.org/0000-0002-5591-6118D. V. Sokolov4https://orcid.org/0000-0002-8120-6638O. N. Semenova5Omsk Scientific Center of Siberian Branch of Russian Academy of Sciences; F. M. Dostoevsky Omsk State UniversityCenter of New Chemical Technologies BIC of Siberian Branch of Russian Academy of SciencesCenter of New Chemical Technologies BIC of Siberian Branch of Russian Academy of SciencesOmsk Scientific Center of Siberian Branch of Russian Academy of Sciences; F. M. Dostoevsky Omsk State UniversityOmsk Scientific Center of Siberian Branch of Russian Academy of SciencesOmsk Scientific Center of Siberian Branch of Russian Academy of SciencesThe work is devoted to solving the urgent task of developing simple ways of applying nanostructured layers of polymers to different substrates with a pairing system with properties of organic semiconductors. To obtain such polymers used dehydrochlorination of polyvinyl chloride under the influence of anilin in the solution dimethylsulfoxide. Iron nitrate is used as a metal-containing modifying supplement. The nanostructured layers of polyvinylen (polymer with the system of conjugated double bonds) are obtained by forming on the plates of monocrystalline quartz by the Langmur-Blodgett. The ASM method shows that in the absence of metal-containing additives, layers of polyvinylens are formed thick ~100 nm. Metal addition leads to significant changes in the morphology of the layers. There is a formation of conglomerates of rounded particles measuring ~30…50 nm. The iron content in these layers is 0,04 % atomic. The study of ultraviolet spectrums shows that iron dopation causes a multiple increase in optical density in the entire range of wavelengths studied. The resulting data can be used to create an elemental base of molecular electronics.https://www.omgtu.ru/general_information/media_omgtu/journal_of_omsk_research_journal/files/arhiv/2019/6%20(168)/83-88%20%D0%9A%D1%80%D0%B8%D0%B2%D0%BE%D0%B7%D1%83%D0%B1%D0%BE%D0%B2%20%D0%9E.%20%D0%92.,%20%D0%9A%D1%80%D1%8F%D0%B6%D0%B5%D0%B2%20%D0%AE.%20%D0%93.,%20%D0%90%D0%BD%D0%B8%D0%BA%D0%B5%D0%B5%D0%B2%D0%B0%20%D0%98.%20%D0%92.%20%D0%B8%20%D0%B4%D1%80..pdfconjugated polymerthin filmspolyvinyl chloridedehydrochlorinatedatomic force microscopyconductivity |
| spellingShingle | O. V. Krivozubov Yu. G. Kryazhev I. V. Anikeeva N. A. Davletkildeev D. V. Sokolov O. N. Semenova Formation on quartz substrate and study of properties of nanostructured layers from polyvinylen obtained by dehydrochlorination of polyvinyl chloride with modifying additive — iron nitrate Омский научный вестник conjugated polymer thin films polyvinyl chloride dehydrochlorinated atomic force microscopy conductivity |
| title | Formation on quartz substrate and study of properties of nanostructured layers from polyvinylen obtained by dehydrochlorination of polyvinyl chloride with modifying additive — iron nitrate |
| title_full | Formation on quartz substrate and study of properties of nanostructured layers from polyvinylen obtained by dehydrochlorination of polyvinyl chloride with modifying additive — iron nitrate |
| title_fullStr | Formation on quartz substrate and study of properties of nanostructured layers from polyvinylen obtained by dehydrochlorination of polyvinyl chloride with modifying additive — iron nitrate |
| title_full_unstemmed | Formation on quartz substrate and study of properties of nanostructured layers from polyvinylen obtained by dehydrochlorination of polyvinyl chloride with modifying additive — iron nitrate |
| title_short | Formation on quartz substrate and study of properties of nanostructured layers from polyvinylen obtained by dehydrochlorination of polyvinyl chloride with modifying additive — iron nitrate |
| title_sort | formation on quartz substrate and study of properties of nanostructured layers from polyvinylen obtained by dehydrochlorination of polyvinyl chloride with modifying additive iron nitrate |
| topic | conjugated polymer thin films polyvinyl chloride dehydrochlorinated atomic force microscopy conductivity |
| url | https://www.omgtu.ru/general_information/media_omgtu/journal_of_omsk_research_journal/files/arhiv/2019/6%20(168)/83-88%20%D0%9A%D1%80%D0%B8%D0%B2%D0%BE%D0%B7%D1%83%D0%B1%D0%BE%D0%B2%20%D0%9E.%20%D0%92.,%20%D0%9A%D1%80%D1%8F%D0%B6%D0%B5%D0%B2%20%D0%AE.%20%D0%93.,%20%D0%90%D0%BD%D0%B8%D0%BA%D0%B5%D0%B5%D0%B2%D0%B0%20%D0%98.%20%D0%92.%20%D0%B8%20%D0%B4%D1%80..pdf |
| work_keys_str_mv | AT ovkrivozubov formationonquartzsubstrateandstudyofpropertiesofnanostructuredlayersfrompolyvinylenobtainedbydehydrochlorinationofpolyvinylchloridewithmodifyingadditiveironnitrate AT yugkryazhev formationonquartzsubstrateandstudyofpropertiesofnanostructuredlayersfrompolyvinylenobtainedbydehydrochlorinationofpolyvinylchloridewithmodifyingadditiveironnitrate AT ivanikeeva formationonquartzsubstrateandstudyofpropertiesofnanostructuredlayersfrompolyvinylenobtainedbydehydrochlorinationofpolyvinylchloridewithmodifyingadditiveironnitrate AT nadavletkildeev formationonquartzsubstrateandstudyofpropertiesofnanostructuredlayersfrompolyvinylenobtainedbydehydrochlorinationofpolyvinylchloridewithmodifyingadditiveironnitrate AT dvsokolov formationonquartzsubstrateandstudyofpropertiesofnanostructuredlayersfrompolyvinylenobtainedbydehydrochlorinationofpolyvinylchloridewithmodifyingadditiveironnitrate AT onsemenova formationonquartzsubstrateandstudyofpropertiesofnanostructuredlayersfrompolyvinylenobtainedbydehydrochlorinationofpolyvinylchloridewithmodifyingadditiveironnitrate |