Comparative analyses of thermodynamic properties assessments, performed by geometric models: Application to the Ni-Bi-Zn system
The thermochemical properties of metals and alloys are essential for the chemists to invent and improve metallurgical and materials’ design processes. However, the properties of multicomponent systems are still scarcely known due to experimental difficulties and the large number of related...
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Main Authors: | , |
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Format: | Article |
Language: | English |
Published: |
University of Belgrade, Technical Faculty, Bor
2013-01-01
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Series: | Journal of Mining and Metallurgy. Section B: Metallurgy |
Subjects: | |
Online Access: | http://www.doiserbia.nb.rs/img/doi/1450-5339/2013/1450-53391300035G.pdf |
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Summary: | The thermochemical properties of metals and alloys are essential for the
chemists to invent and improve metallurgical and materials’ design processes.
However, the properties of multicomponent systems are still scarcely known
due to experimental difficulties and the large number of related systems.
Thus, the modelling of some thermodynamic properties would be advantageous
when experimental data are missing. Considering mentioned facts, geometric
models to estimate some thermodynamic properties for the liquid phase of the
Ni-Bi-Zn systems. The calculations have been performed in a wide temperature
range (1000-2000 K). Ternary interaction parameters for the liquid phase
allowing molar Gibbs excess energy calculation have been determined. |
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ISSN: | 1450-5339 |