Microarticstructural, Spectroscopic, and Magnetic Analysis of Multiwalled Carbon Nanotubes Embedded in Poly (o-aminophenol) Matrices

This paper describes a one-step chemically produced multiwalled carbon nanotubes/poly-ortho-aminophenol (MWCNTs/PoAP) nanocomposite film production process using in-situ oxidative polymerization. The CoCl2-doped nanocomposites exhibit good stability and increased magnetic performance. The morphologi...

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Main Authors: null Sonika, Sushil Kumar Verma, J. Saha, Rim M. Alsharabi, Shailendra Rajput
Format: Article
Language:English
Published: Wiley 2022-01-01
Series:Advances in Materials Science and Engineering
Online Access:http://dx.doi.org/10.1155/2022/5437954
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author null Sonika
Sushil Kumar Verma
J. Saha
Rim M. Alsharabi
Shailendra Rajput
author_facet null Sonika
Sushil Kumar Verma
J. Saha
Rim M. Alsharabi
Shailendra Rajput
author_sort null Sonika
collection DOAJ
description This paper describes a one-step chemically produced multiwalled carbon nanotubes/poly-ortho-aminophenol (MWCNTs/PoAP) nanocomposite film production process using in-situ oxidative polymerization. The CoCl2-doped nanocomposites exhibit good stability and increased magnetic performance. The morphological analysis revealed that PoAP deposits on the surface of the nanoparticle result in the creation of a fibrous crystal-like structure. The vibrational spectra show that there is a substantial interaction between PoAP and MWCNT/MWCNT[-COOH]. The introduction of nanocrystalline MWCNTS increases PoAP’s UV absorption and causes a blue shift in π-polaron absorption. The magnetic study of Co-doped MWCNTs/PoAP nanocomposites has shown a marked reduction in the hysteresis behavior, indicating significant hole doping associated with the oxygen functional groups on the surface of xidized carbon ’nanotubes. The syntheses of nanocomposites are silent features of the work with implications in crystal engineering and nanocomposite design for various applications.
format Article
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institution Kabale University
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publishDate 2022-01-01
publisher Wiley
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series Advances in Materials Science and Engineering
spelling doaj-art-c6955ece784b4e4d9d91d6a25187248d2025-02-03T11:54:03ZengWileyAdvances in Materials Science and Engineering1687-84422022-01-01202210.1155/2022/5437954Microarticstructural, Spectroscopic, and Magnetic Analysis of Multiwalled Carbon Nanotubes Embedded in Poly (o-aminophenol) Matricesnull Sonika0Sushil Kumar Verma1J. Saha2Rim M. Alsharabi3Shailendra Rajput4Department of PhysicsDepartment of Chemical EngineeringDepartment of PhysicsDepartment of PhysicsDepartment of PhysicsThis paper describes a one-step chemically produced multiwalled carbon nanotubes/poly-ortho-aminophenol (MWCNTs/PoAP) nanocomposite film production process using in-situ oxidative polymerization. The CoCl2-doped nanocomposites exhibit good stability and increased magnetic performance. The morphological analysis revealed that PoAP deposits on the surface of the nanoparticle result in the creation of a fibrous crystal-like structure. The vibrational spectra show that there is a substantial interaction between PoAP and MWCNT/MWCNT[-COOH]. The introduction of nanocrystalline MWCNTS increases PoAP’s UV absorption and causes a blue shift in π-polaron absorption. The magnetic study of Co-doped MWCNTs/PoAP nanocomposites has shown a marked reduction in the hysteresis behavior, indicating significant hole doping associated with the oxygen functional groups on the surface of xidized carbon ’nanotubes. The syntheses of nanocomposites are silent features of the work with implications in crystal engineering and nanocomposite design for various applications.http://dx.doi.org/10.1155/2022/5437954
spellingShingle null Sonika
Sushil Kumar Verma
J. Saha
Rim M. Alsharabi
Shailendra Rajput
Microarticstructural, Spectroscopic, and Magnetic Analysis of Multiwalled Carbon Nanotubes Embedded in Poly (o-aminophenol) Matrices
Advances in Materials Science and Engineering
title Microarticstructural, Spectroscopic, and Magnetic Analysis of Multiwalled Carbon Nanotubes Embedded in Poly (o-aminophenol) Matrices
title_full Microarticstructural, Spectroscopic, and Magnetic Analysis of Multiwalled Carbon Nanotubes Embedded in Poly (o-aminophenol) Matrices
title_fullStr Microarticstructural, Spectroscopic, and Magnetic Analysis of Multiwalled Carbon Nanotubes Embedded in Poly (o-aminophenol) Matrices
title_full_unstemmed Microarticstructural, Spectroscopic, and Magnetic Analysis of Multiwalled Carbon Nanotubes Embedded in Poly (o-aminophenol) Matrices
title_short Microarticstructural, Spectroscopic, and Magnetic Analysis of Multiwalled Carbon Nanotubes Embedded in Poly (o-aminophenol) Matrices
title_sort microarticstructural spectroscopic and magnetic analysis of multiwalled carbon nanotubes embedded in poly o aminophenol matrices
url http://dx.doi.org/10.1155/2022/5437954
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AT jsaha microarticstructuralspectroscopicandmagneticanalysisofmultiwalledcarbonnanotubesembeddedinpolyoaminophenolmatrices
AT rimmalsharabi microarticstructuralspectroscopicandmagneticanalysisofmultiwalledcarbonnanotubesembeddedinpolyoaminophenolmatrices
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