Surprising acidity for the methylene of 1,3-indenocorannulenes?

Surprising acidity for the methylene of 1,3-indenocorannulenes?

Quantitative assessment of the first acidity constant (pKa) for BFC (27.6 in CH3CN) and FIC (27.8 in CH3CN) shows the methylene protons to be significantly more acidic than those in related cyclopentadiene (32 in CH3CN), indene (34 in CH3CN), or fluorene (37 in CH3CN) and comparable to the methine o...

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Bibliographic Details
Main Authors: Shi Liu, Märt Lõkov, Sofja Tshepelevitsh, Ivo Leito, Kim K. Baldridge, Jay S. Siegel
Format: Article
Language:English
Published: Beilstein-Institut 2024-12-01
Series:Beilstein Journal of Organic Chemistry
Subjects:
acidity
aromatic hydrocarbon
clar sextet
loschmidt group element
molecular graph
Online Access:https://doi.org/10.3762/bjoc.20.260
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https://doi.org/10.3762/bjoc.20.260

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