Ionic-Liquid-Mediated MacMillan’s Catalyst for Diels-Alder Reaction

Ionic liquids were used to enhance as well as recycle the MacMillan's catalyst 1 for the Diels-Alder reaction. Using our developed protocol, Diels-Alder adducts were obtained in good yields and selectivities along the 6 times recycling of MacMillan's imidazolidinone catalyst 1. Synthesis o...

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Main Author: Vivek Srivastava
Format: Article
Language:English
Published: Wiley 2013-01-01
Series:Journal of Chemistry
Online Access:http://dx.doi.org/10.1155/2013/954094
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author Vivek Srivastava
author_facet Vivek Srivastava
author_sort Vivek Srivastava
collection DOAJ
description Ionic liquids were used to enhance as well as recycle the MacMillan's catalyst 1 for the Diels-Alder reaction. Using our developed protocol, Diels-Alder adducts were obtained in good yields and selectivities along the 6 times recycling of MacMillan's imidazolidinone catalyst 1. Synthesis of steroid 4 is the major outcome of our developed protocol.
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institution Kabale University
issn 2090-9063
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language English
publishDate 2013-01-01
publisher Wiley
record_format Article
series Journal of Chemistry
spelling doaj-art-c59ed1cbd88d4b8ab81b20fa4b88ff562025-02-03T05:59:18ZengWileyJournal of Chemistry2090-90632090-90712013-01-01201310.1155/2013/954094954094Ionic-Liquid-Mediated MacMillan’s Catalyst for Diels-Alder ReactionVivek Srivastava0Applied Science, NIIT University, Neemrana, Alwar, Rajasthan 301705, IndiaIonic liquids were used to enhance as well as recycle the MacMillan's catalyst 1 for the Diels-Alder reaction. Using our developed protocol, Diels-Alder adducts were obtained in good yields and selectivities along the 6 times recycling of MacMillan's imidazolidinone catalyst 1. Synthesis of steroid 4 is the major outcome of our developed protocol.http://dx.doi.org/10.1155/2013/954094
spellingShingle Vivek Srivastava
Ionic-Liquid-Mediated MacMillan’s Catalyst for Diels-Alder Reaction
Journal of Chemistry
title Ionic-Liquid-Mediated MacMillan’s Catalyst for Diels-Alder Reaction
title_full Ionic-Liquid-Mediated MacMillan’s Catalyst for Diels-Alder Reaction
title_fullStr Ionic-Liquid-Mediated MacMillan’s Catalyst for Diels-Alder Reaction
title_full_unstemmed Ionic-Liquid-Mediated MacMillan’s Catalyst for Diels-Alder Reaction
title_short Ionic-Liquid-Mediated MacMillan’s Catalyst for Diels-Alder Reaction
title_sort ionic liquid mediated macmillan s catalyst for diels alder reaction
url http://dx.doi.org/10.1155/2013/954094
work_keys_str_mv AT viveksrivastava ionicliquidmediatedmacmillanscatalystfordielsalderreaction