Enhancement of Single‐Molecule Magnet Properties by Manipulating Intramolecular Dipolar Interactions

Abstract A new single‐molecule magnet (SMM) complex [K(18‐crown‐6)][(COT)Er(µ‐Cl)3Er(COT)] (Er2Cl3, COT = cyclooctatetraenide dianion) is obtained by the reaction of [(COT)Er(µ‐Cl)(THF)]2 (Er2Cl2, THF = tetrahydrofuran) with an equivalent of KCl in the presence of 18‐crown‐6. The two COT‐Er units in...

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Bibliographic Details
Main Authors: Jia‐Qi Huang, Qi‐Wei Chen, You‐Song Ding, Xiao‐Fei Zhu, Bing‐Wu Wang, Feng Pan, Zhiping Zheng
Format: Article
Language:English
Published: Wiley 2025-01-01
Series:Advanced Science
Subjects:
Online Access:https://doi.org/10.1002/advs.202409730
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