Recovery of Hg(0) from the Aqueous Hg(I/II) Present in Analyte Solution after Quantitative Determination of Iron

An easy and feasible approach to recover HgCl2, used in quantitative determination of iron values, as Hg(0) was described. Both Hg(I) and Hg(II), present in the solution after quantitative determination of iron, was completely reduced to Hg(0) by the addition of aluminium chips in more slightly exce...

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Main Authors: Suman K. Giri, Nigamananda Das
Format: Article
Language:English
Published: Wiley 2013-01-01
Series:Journal of Chemistry
Online Access:http://dx.doi.org/10.1155/2013/609590
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author Suman K. Giri
Nigamananda Das
author_facet Suman K. Giri
Nigamananda Das
author_sort Suman K. Giri
collection DOAJ
description An easy and feasible approach to recover HgCl2, used in quantitative determination of iron values, as Hg(0) was described. Both Hg(I) and Hg(II), present in the solution after quantitative determination of iron, was completely reduced to Hg(0) by the addition of aluminium chips in more slightly excess than the stoichiometric amount. The purity of recovered Hg(0) was verified by comparing the value of density with pure mercury. This simple method may be useful to remove the mercury from other waste aqueous solutions before their discharge into the environment.
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institution Kabale University
issn 2090-9063
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spelling doaj-art-c41738ccb93b423eacf1ddd638f79d1d2025-02-03T01:03:29ZengWileyJournal of Chemistry2090-90632090-90712013-01-01201310.1155/2013/609590609590Recovery of Hg(0) from the Aqueous Hg(I/II) Present in Analyte Solution after Quantitative Determination of IronSuman K. Giri0Nigamananda Das1Department of Chemistry, Utkal University, Orissa, Bhubaneswar 751 004, IndiaDepartment of Chemistry, North Orissa University, Orissa, Baripada 757 003, IndiaAn easy and feasible approach to recover HgCl2, used in quantitative determination of iron values, as Hg(0) was described. Both Hg(I) and Hg(II), present in the solution after quantitative determination of iron, was completely reduced to Hg(0) by the addition of aluminium chips in more slightly excess than the stoichiometric amount. The purity of recovered Hg(0) was verified by comparing the value of density with pure mercury. This simple method may be useful to remove the mercury from other waste aqueous solutions before their discharge into the environment.http://dx.doi.org/10.1155/2013/609590
spellingShingle Suman K. Giri
Nigamananda Das
Recovery of Hg(0) from the Aqueous Hg(I/II) Present in Analyte Solution after Quantitative Determination of Iron
Journal of Chemistry
title Recovery of Hg(0) from the Aqueous Hg(I/II) Present in Analyte Solution after Quantitative Determination of Iron
title_full Recovery of Hg(0) from the Aqueous Hg(I/II) Present in Analyte Solution after Quantitative Determination of Iron
title_fullStr Recovery of Hg(0) from the Aqueous Hg(I/II) Present in Analyte Solution after Quantitative Determination of Iron
title_full_unstemmed Recovery of Hg(0) from the Aqueous Hg(I/II) Present in Analyte Solution after Quantitative Determination of Iron
title_short Recovery of Hg(0) from the Aqueous Hg(I/II) Present in Analyte Solution after Quantitative Determination of Iron
title_sort recovery of hg 0 from the aqueous hg i ii present in analyte solution after quantitative determination of iron
url http://dx.doi.org/10.1155/2013/609590
work_keys_str_mv AT sumankgiri recoveryofhg0fromtheaqueoushgiiipresentinanalytesolutionafterquantitativedeterminationofiron
AT nigamanandadas recoveryofhg0fromtheaqueoushgiiipresentinanalytesolutionafterquantitativedeterminationofiron