Why the Real Atmosphere Has More Energy than Climate Models: Implications for Ground-Based Telescopes

The calculation of Gibbs free energy via the statistical multifractal analysis of airborne observations indicates that the atmosphere is not at local thermodynamic equilibrium. Both climate models and meteorological analyses assume that it is. Satellite retrievals use spectroscopic data taken at equ...

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Main Author: Adrian F. Tuck
Format: Article
Language:English
Published: MDPI AG 2025-01-01
Series:Atmosphere
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Online Access:https://www.mdpi.com/2073-4433/16/1/56
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author Adrian F. Tuck
author_facet Adrian F. Tuck
author_sort Adrian F. Tuck
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description The calculation of Gibbs free energy via the statistical multifractal analysis of airborne observations indicates that the atmosphere is not at local thermodynamic equilibrium. Both climate models and meteorological analyses assume that it is. Satellite retrievals use spectroscopic data taken at equilibrium in laboratories, leading to apparent consistency that is to some degree faulty. Line shapes of radiatively active species, the rotational energy of molecular nitrogen and oxygen, and the translational energy of all molecules are involved, resulting in less energy in models than exists in the real atmosphere. The resulting formulation of turbulence is from the smallest scales up and has implications for astronomical observation by adaptive optics. Kolmogorov (isotropy) is not evident. The effect of temperature on the overhead water vapour column at ground-based telescopes is also open to the effects of climate change. The degree to which the dynamic operational temperature differs from that obtained by the use of local thermodynamic equilibrium assumptions needs to be established by observational measurements. Some of the considerations will apply to the atmospheres of exoplanets with regard to photochemistry and signatures of life.
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spelling doaj-art-c1bc8dfb7cf24cd4b5160965d5a4864f2025-01-24T13:21:52ZengMDPI AGAtmosphere2073-44332025-01-011615610.3390/atmos16010056Why the Real Atmosphere Has More Energy than Climate Models: Implications for Ground-Based TelescopesAdrian F. Tuck0Independent Researcher, Boulder, CO 80303, USAThe calculation of Gibbs free energy via the statistical multifractal analysis of airborne observations indicates that the atmosphere is not at local thermodynamic equilibrium. Both climate models and meteorological analyses assume that it is. Satellite retrievals use spectroscopic data taken at equilibrium in laboratories, leading to apparent consistency that is to some degree faulty. Line shapes of radiatively active species, the rotational energy of molecular nitrogen and oxygen, and the translational energy of all molecules are involved, resulting in less energy in models than exists in the real atmosphere. The resulting formulation of turbulence is from the smallest scales up and has implications for astronomical observation by adaptive optics. Kolmogorov (isotropy) is not evident. The effect of temperature on the overhead water vapour column at ground-based telescopes is also open to the effects of climate change. The degree to which the dynamic operational temperature differs from that obtained by the use of local thermodynamic equilibrium assumptions needs to be established by observational measurements. Some of the considerations will apply to the atmospheres of exoplanets with regard to photochemistry and signatures of life.https://www.mdpi.com/2073-4433/16/1/56statistical multifractalsGibbs free energymolecular velocitiessymmetry breakingturbulenceatmospheric energy
spellingShingle Adrian F. Tuck
Why the Real Atmosphere Has More Energy than Climate Models: Implications for Ground-Based Telescopes
Atmosphere
statistical multifractals
Gibbs free energy
molecular velocities
symmetry breaking
turbulence
atmospheric energy
title Why the Real Atmosphere Has More Energy than Climate Models: Implications for Ground-Based Telescopes
title_full Why the Real Atmosphere Has More Energy than Climate Models: Implications for Ground-Based Telescopes
title_fullStr Why the Real Atmosphere Has More Energy than Climate Models: Implications for Ground-Based Telescopes
title_full_unstemmed Why the Real Atmosphere Has More Energy than Climate Models: Implications for Ground-Based Telescopes
title_short Why the Real Atmosphere Has More Energy than Climate Models: Implications for Ground-Based Telescopes
title_sort why the real atmosphere has more energy than climate models implications for ground based telescopes
topic statistical multifractals
Gibbs free energy
molecular velocities
symmetry breaking
turbulence
atmospheric energy
url https://www.mdpi.com/2073-4433/16/1/56
work_keys_str_mv AT adrianftuck whytherealatmospherehasmoreenergythanclimatemodelsimplicationsforgroundbasedtelescopes