Synthesis and structural characterization of the dichloride complex formed by carboxy-functionalized Cu(diazacyclam)2+ cation and its heterometallic coordination polymer with CdCl2

Synthesis and structural characterization of the dichloride complex formed by carboxy-functionalized Cu(diazacyclam)2+ cation and its heterometallic coordination polymer with CdCl2

The asymmetric unit of the complex [3,10-bis(3-carboxypropyl)-1,3,5,8,10,12-hexaazacyclotetradecane-κ4N1,N5,N8,N12]dichloridocopper(II), [CuCl2(C16H34N6O4)] or [Cu(H2L)Cl2] (I), consists of a centrosymmetric macrocyclic CuII dication and a chloride anion. The components of the heterometallic compoun...

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Bibliographic Details
Main Authors: Liudmyla V. Tsymbal, Irina L. Andriichuk, Alexandru-Constantin Stoica, Yaroslaw D. Lampeka
Format: Article
Language:English
Published: International Union of Crystallography 2025-06-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
crystal structure
diazacyclam
3-carboxypropyl substituent
copper
cadmium
coordination polymer
hydrogen bonds.
Online Access:https://journals.iucr.org/paper?S2056989025003792
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