Copper(II) Extraction from Nitric Acid Solution with 1-Phenyl-3-methyl-4-benzoyl-5-pyrazolone as a Cation Carrier by Liquid Membrane Emulsion
Copper(II) extraction from nitric acid solution with 1-phenyl-3-methyl-4-benzoil-5-pyrazolone (HPMBP) as a cation carrier by liquid membrane emulsion (LME) was investigated. The HPMBP initially was synthesized and the synthesis yield is a yellow crystal with melting point of 87-89 °C. The synthesis...
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| Format: | Article |
| Language: | English |
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Wiley
2010-01-01
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| Series: | E-Journal of Chemistry |
| Online Access: | http://dx.doi.org/10.1155/2010/235274 |
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| author | Baharuddin Hamzah Noor Jalaluddin Abdul Wahid Wahab Ambo Upe |
| author_facet | Baharuddin Hamzah Noor Jalaluddin Abdul Wahid Wahab Ambo Upe |
| author_sort | Baharuddin Hamzah |
| collection | DOAJ |
| description | Copper(II) extraction from nitric acid solution with 1-phenyl-3-methyl-4-benzoil-5-pyrazolone (HPMBP) as a cation carrier by liquid membrane emulsion (LME) was investigated. The HPMBP initially was synthesized and the synthesis yield is a yellow crystal with melting point of 87-89 °C. The synthesis efficiency is 72.04% and generally the spectra of IR, 1H NMR and 13C NMR agree with HPMBP structure. The optimum condition for copper(II) extraction were found as follows: concentration of mixed surfactant (span 80+span 20) was 3%, volume ratio of membrane and internal phase was 1, concentration of HPMBP was 0.020 M, concentration of HCl was 1 M, volume ratio of emulsion and external phase was 0.143. By using these optimum conditions, 30 mL of LME can extract 1000 ppm of copper(II) within 210 mL of nitric acid solution with extraction percentage of 97.97%. |
| format | Article |
| id | doaj-art-b8264f6f9c804042803440b61bcb982f |
| institution | Kabale University |
| issn | 0973-4945 2090-9810 |
| language | English |
| publishDate | 2010-01-01 |
| publisher | Wiley |
| record_format | Article |
| series | E-Journal of Chemistry |
| spelling | doaj-art-b8264f6f9c804042803440b61bcb982f2025-02-03T01:24:31ZengWileyE-Journal of Chemistry0973-49452090-98102010-01-017123924510.1155/2010/235274Copper(II) Extraction from Nitric Acid Solution with 1-Phenyl-3-methyl-4-benzoyl-5-pyrazolone as a Cation Carrier by Liquid Membrane EmulsionBaharuddin Hamzah0Noor Jalaluddin1Abdul Wahid Wahab2Ambo Upe3Faculty of Teacher Training and Education, Universitas Tadulako Palu, Kampus Bumi Tadulako Tondo, 94223 Palu, IndonesiaFaculty of Mathematics and Natural Science, Universitas Hasanuddin Makassar, Kampus Tamalanrea, 90245 Makassar, IndonesiaFaculty of Mathematics and Natural Science, Universitas Hasanuddin Makassar, Kampus Tamalanrea, 90245 Makassar, IndonesiaFaculty of Mathematics and Natural Science, Universitas Hasanuddin Makassar, Kampus Tamalanrea, 90245 Makassar, IndonesiaCopper(II) extraction from nitric acid solution with 1-phenyl-3-methyl-4-benzoil-5-pyrazolone (HPMBP) as a cation carrier by liquid membrane emulsion (LME) was investigated. The HPMBP initially was synthesized and the synthesis yield is a yellow crystal with melting point of 87-89 °C. The synthesis efficiency is 72.04% and generally the spectra of IR, 1H NMR and 13C NMR agree with HPMBP structure. The optimum condition for copper(II) extraction were found as follows: concentration of mixed surfactant (span 80+span 20) was 3%, volume ratio of membrane and internal phase was 1, concentration of HPMBP was 0.020 M, concentration of HCl was 1 M, volume ratio of emulsion and external phase was 0.143. By using these optimum conditions, 30 mL of LME can extract 1000 ppm of copper(II) within 210 mL of nitric acid solution with extraction percentage of 97.97%.http://dx.doi.org/10.1155/2010/235274 |
| spellingShingle | Baharuddin Hamzah Noor Jalaluddin Abdul Wahid Wahab Ambo Upe Copper(II) Extraction from Nitric Acid Solution with 1-Phenyl-3-methyl-4-benzoyl-5-pyrazolone as a Cation Carrier by Liquid Membrane Emulsion E-Journal of Chemistry |
| title | Copper(II) Extraction from Nitric Acid Solution with 1-Phenyl-3-methyl-4-benzoyl-5-pyrazolone as a Cation Carrier by Liquid Membrane Emulsion |
| title_full | Copper(II) Extraction from Nitric Acid Solution with 1-Phenyl-3-methyl-4-benzoyl-5-pyrazolone as a Cation Carrier by Liquid Membrane Emulsion |
| title_fullStr | Copper(II) Extraction from Nitric Acid Solution with 1-Phenyl-3-methyl-4-benzoyl-5-pyrazolone as a Cation Carrier by Liquid Membrane Emulsion |
| title_full_unstemmed | Copper(II) Extraction from Nitric Acid Solution with 1-Phenyl-3-methyl-4-benzoyl-5-pyrazolone as a Cation Carrier by Liquid Membrane Emulsion |
| title_short | Copper(II) Extraction from Nitric Acid Solution with 1-Phenyl-3-methyl-4-benzoyl-5-pyrazolone as a Cation Carrier by Liquid Membrane Emulsion |
| title_sort | copper ii extraction from nitric acid solution with 1 phenyl 3 methyl 4 benzoyl 5 pyrazolone as a cation carrier by liquid membrane emulsion |
| url | http://dx.doi.org/10.1155/2010/235274 |
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