Green Synthesis of Iron Nanoparticles: Application on the Removal of Petroleum Oil from Contaminated Water and Soils

Iron nanoparticles were produced using the extract of mortiño berry (Vaccinium floribundum) (vZVI) as reducing and stabilizer agent. Fresh nanoparticles were characterized using TEM, XRD, and FTIR techniques, while laboratory experiments were conducted to assess the removal of total petroleum hydroc...

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Main Authors: Erika Murgueitio, Luis Cumbal, Mayra Abril, Andrés Izquierdo, Alexis Debut, Oscar Tinoco
Format: Article
Language:English
Published: Wiley 2018-01-01
Series:Journal of Nanotechnology
Online Access:http://dx.doi.org/10.1155/2018/4184769
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author Erika Murgueitio
Luis Cumbal
Mayra Abril
Andrés Izquierdo
Alexis Debut
Oscar Tinoco
author_facet Erika Murgueitio
Luis Cumbal
Mayra Abril
Andrés Izquierdo
Alexis Debut
Oscar Tinoco
author_sort Erika Murgueitio
collection DOAJ
description Iron nanoparticles were produced using the extract of mortiño berry (Vaccinium floribundum) (vZVI) as reducing and stabilizer agent. Fresh nanoparticles were characterized using TEM, XRD, and FTIR techniques, while laboratory experiments were conducted to assess the removal of total petroleum hydrocarbons (TPHs) from water and soil after treatment with synthesized nanoscale iron particles. Nanoparticles as produced were spherical in the range of 5–10 nm. After treatment with vZVI nanoparticles, water contaminated with two concentrations of TPHs (9.32 mg/L and 94.20 mg/L) showed removals of 85.94% and 88.34%, respectively, whereas a contaminated soil with a TPHs concentration of 5000 mg/kg treated during 32 h with nanoparticles reached a removal of 81.90%. Results indicate that the addition of vZVI nanoparticles produced strong reducing conditions, which accelerate removal of TPHs and suggest that these nanoparticles might be a promising technology to clean up TPHs contaminated water and soils.
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institution Kabale University
issn 1687-9503
1687-9511
language English
publishDate 2018-01-01
publisher Wiley
record_format Article
series Journal of Nanotechnology
spelling doaj-art-b243d8ed8ec044a78876ecc45d02bc972025-02-03T05:44:14ZengWileyJournal of Nanotechnology1687-95031687-95112018-01-01201810.1155/2018/41847694184769Green Synthesis of Iron Nanoparticles: Application on the Removal of Petroleum Oil from Contaminated Water and SoilsErika Murgueitio0Luis Cumbal1Mayra Abril2Andrés Izquierdo3Alexis Debut4Oscar Tinoco5Centro de Nanociencia y Nanotecnología, Universidad de las Fuerzas Armadas ESPE, Av. Gral. Rumiñahui s/n, P.O. Box 171-5-231B, Sangolquí, EcuadorCentro de Nanociencia y Nanotecnología, Universidad de las Fuerzas Armadas ESPE, Av. Gral. Rumiñahui s/n, P.O. Box 171-5-231B, Sangolquí, EcuadorCentro de Nanociencia y Nanotecnología, Universidad de las Fuerzas Armadas ESPE, Av. Gral. Rumiñahui s/n, P.O. Box 171-5-231B, Sangolquí, EcuadorCentro de Nanociencia y Nanotecnología, Universidad de las Fuerzas Armadas ESPE, Av. Gral. Rumiñahui s/n, P.O. Box 171-5-231B, Sangolquí, EcuadorCentro de Nanociencia y Nanotecnología, Universidad de las Fuerzas Armadas ESPE, Av. Gral. Rumiñahui s/n, P.O. Box 171-5-231B, Sangolquí, EcuadorUnidad de Posgrado, Facultad de Ingeniería Geológica, Minera, Metalúrgica y Geográfica, Doctorado en Ciencias Ambientales, Universidad Nacional Mayor de San Marcos, Lima, PeruIron nanoparticles were produced using the extract of mortiño berry (Vaccinium floribundum) (vZVI) as reducing and stabilizer agent. Fresh nanoparticles were characterized using TEM, XRD, and FTIR techniques, while laboratory experiments were conducted to assess the removal of total petroleum hydrocarbons (TPHs) from water and soil after treatment with synthesized nanoscale iron particles. Nanoparticles as produced were spherical in the range of 5–10 nm. After treatment with vZVI nanoparticles, water contaminated with two concentrations of TPHs (9.32 mg/L and 94.20 mg/L) showed removals of 85.94% and 88.34%, respectively, whereas a contaminated soil with a TPHs concentration of 5000 mg/kg treated during 32 h with nanoparticles reached a removal of 81.90%. Results indicate that the addition of vZVI nanoparticles produced strong reducing conditions, which accelerate removal of TPHs and suggest that these nanoparticles might be a promising technology to clean up TPHs contaminated water and soils.http://dx.doi.org/10.1155/2018/4184769
spellingShingle Erika Murgueitio
Luis Cumbal
Mayra Abril
Andrés Izquierdo
Alexis Debut
Oscar Tinoco
Green Synthesis of Iron Nanoparticles: Application on the Removal of Petroleum Oil from Contaminated Water and Soils
Journal of Nanotechnology
title Green Synthesis of Iron Nanoparticles: Application on the Removal of Petroleum Oil from Contaminated Water and Soils
title_full Green Synthesis of Iron Nanoparticles: Application on the Removal of Petroleum Oil from Contaminated Water and Soils
title_fullStr Green Synthesis of Iron Nanoparticles: Application on the Removal of Petroleum Oil from Contaminated Water and Soils
title_full_unstemmed Green Synthesis of Iron Nanoparticles: Application on the Removal of Petroleum Oil from Contaminated Water and Soils
title_short Green Synthesis of Iron Nanoparticles: Application on the Removal of Petroleum Oil from Contaminated Water and Soils
title_sort green synthesis of iron nanoparticles application on the removal of petroleum oil from contaminated water and soils
url http://dx.doi.org/10.1155/2018/4184769
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