Protected Geographical Indication Identification of a Chinese Green Tea (Anji-White) by Near-Infrared Spectroscopy and Chemometric Class Modeling Techniques

This paper reports a rapid identification method for a Chinese green tea with PGI, Anji-white tea, by class modeling techniques and NIR spectroscopy. 167 real and representative Anji-white tea samples were collected from 8 tea plantations in their original producing areas for model training. Another...

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Main Authors: Lu Xu, Peng-Tao Shi, Xian-Shu Fu, Hai-Feng Cui, Zi-Hong Ye, Chen-Bo Cai, Xiao-Ping Yu
Format: Article
Language:English
Published: Wiley 2013-01-01
Series:Journal of Spectroscopy
Online Access:http://dx.doi.org/10.1155/2013/501924
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author Lu Xu
Peng-Tao Shi
Xian-Shu Fu
Hai-Feng Cui
Zi-Hong Ye
Chen-Bo Cai
Xiao-Ping Yu
author_facet Lu Xu
Peng-Tao Shi
Xian-Shu Fu
Hai-Feng Cui
Zi-Hong Ye
Chen-Bo Cai
Xiao-Ping Yu
author_sort Lu Xu
collection DOAJ
description This paper reports a rapid identification method for a Chinese green tea with PGI, Anji-white tea, by class modeling techniques and NIR spectroscopy. 167 real and representative Anji-white tea samples were collected from 8 tea plantations in their original producing areas for model training. Another 81 non-Anji-white tea samples of similar appearance were collected from 7 important tea producing areas and used for validation of model specificity. Diffuse NIR spectra were measured with finely ground tea powders. OCPLS and SIMCA were used to describe the distribution of representative Anji-white tea objects and predict the authenticity of new objects. For data preprocessing, smoothing, derivatives, and SNV were applied to improve the raw spectra and classification performance. It is demonstrated that taking derivatives and SNV can improve classification accuracy and reduce the complexity of class models by removing spectral background and baseline. For the best models, the sensitivity and specificity were 0.886 and 0.951 for OCPLS, 0.886 and 0.938 for SIMCA with SNV spectra, respectively. Although it is difficult to perform an exhaustive analysis of all types of potential false objects, the proposed method can detect most of the important non-Anji-white teas in the Chinese market.
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id doaj-art-b13208e6b70c44e8a340d9dc1ea85333
institution Kabale University
issn 2314-4920
2314-4939
language English
publishDate 2013-01-01
publisher Wiley
record_format Article
series Journal of Spectroscopy
spelling doaj-art-b13208e6b70c44e8a340d9dc1ea853332025-02-03T05:51:28ZengWileyJournal of Spectroscopy2314-49202314-49392013-01-01201310.1155/2013/501924501924Protected Geographical Indication Identification of a Chinese Green Tea (Anji-White) by Near-Infrared Spectroscopy and Chemometric Class Modeling TechniquesLu Xu0Peng-Tao Shi1Xian-Shu Fu2Hai-Feng Cui3Zi-Hong Ye4Chen-Bo Cai5Xiao-Ping Yu6Zhejiang Provincial Key Laboratory of Biometrology and Inspection & Quarantine, College of Life Sciences, China Jiliang University, Hangzhou 310018, ChinaZhejiang Provincial Key Laboratory of Biometrology and Inspection & Quarantine, College of Life Sciences, China Jiliang University, Hangzhou 310018, ChinaZhejiang Provincial Key Laboratory of Biometrology and Inspection & Quarantine, College of Life Sciences, China Jiliang University, Hangzhou 310018, ChinaZhejiang Provincial Key Laboratory of Biometrology and Inspection & Quarantine, College of Life Sciences, China Jiliang University, Hangzhou 310018, ChinaZhejiang Provincial Key Laboratory of Biometrology and Inspection & Quarantine, College of Life Sciences, China Jiliang University, Hangzhou 310018, ChinaDepartment of Chemistry and Life Science, Chuxiong Normal University, Chuxiong 675000, ChinaZhejiang Provincial Key Laboratory of Biometrology and Inspection & Quarantine, College of Life Sciences, China Jiliang University, Hangzhou 310018, ChinaThis paper reports a rapid identification method for a Chinese green tea with PGI, Anji-white tea, by class modeling techniques and NIR spectroscopy. 167 real and representative Anji-white tea samples were collected from 8 tea plantations in their original producing areas for model training. Another 81 non-Anji-white tea samples of similar appearance were collected from 7 important tea producing areas and used for validation of model specificity. Diffuse NIR spectra were measured with finely ground tea powders. OCPLS and SIMCA were used to describe the distribution of representative Anji-white tea objects and predict the authenticity of new objects. For data preprocessing, smoothing, derivatives, and SNV were applied to improve the raw spectra and classification performance. It is demonstrated that taking derivatives and SNV can improve classification accuracy and reduce the complexity of class models by removing spectral background and baseline. For the best models, the sensitivity and specificity were 0.886 and 0.951 for OCPLS, 0.886 and 0.938 for SIMCA with SNV spectra, respectively. Although it is difficult to perform an exhaustive analysis of all types of potential false objects, the proposed method can detect most of the important non-Anji-white teas in the Chinese market.http://dx.doi.org/10.1155/2013/501924
spellingShingle Lu Xu
Peng-Tao Shi
Xian-Shu Fu
Hai-Feng Cui
Zi-Hong Ye
Chen-Bo Cai
Xiao-Ping Yu
Protected Geographical Indication Identification of a Chinese Green Tea (Anji-White) by Near-Infrared Spectroscopy and Chemometric Class Modeling Techniques
Journal of Spectroscopy
title Protected Geographical Indication Identification of a Chinese Green Tea (Anji-White) by Near-Infrared Spectroscopy and Chemometric Class Modeling Techniques
title_full Protected Geographical Indication Identification of a Chinese Green Tea (Anji-White) by Near-Infrared Spectroscopy and Chemometric Class Modeling Techniques
title_fullStr Protected Geographical Indication Identification of a Chinese Green Tea (Anji-White) by Near-Infrared Spectroscopy and Chemometric Class Modeling Techniques
title_full_unstemmed Protected Geographical Indication Identification of a Chinese Green Tea (Anji-White) by Near-Infrared Spectroscopy and Chemometric Class Modeling Techniques
title_short Protected Geographical Indication Identification of a Chinese Green Tea (Anji-White) by Near-Infrared Spectroscopy and Chemometric Class Modeling Techniques
title_sort protected geographical indication identification of a chinese green tea anji white by near infrared spectroscopy and chemometric class modeling techniques
url http://dx.doi.org/10.1155/2013/501924
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