Evaluation of Thermal Stress and Performance for Solid Oxide Electrolysis Cells Employing Graded Fuel Electrodes

An electrochemical reactions coupled multi-physics model is developed and applied to elucidate overall performance and thermal stress distributed in solid oxide electrolysis cells (SOECs) with graded fuel electrodes. Extending the conventional fuel electrode, the effects of various graded parameters...

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Main Authors: Fangzheng Liu, Liusheng Xiao, Ruidong Zhou, Qi Liu, Jinliang Yuan
Format: Article
Language:English
Published: MDPI AG 2025-05-01
Series:Energies
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Online Access:https://www.mdpi.com/1996-1073/18/11/2790
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author Fangzheng Liu
Liusheng Xiao
Ruidong Zhou
Qi Liu
Jinliang Yuan
author_facet Fangzheng Liu
Liusheng Xiao
Ruidong Zhou
Qi Liu
Jinliang Yuan
author_sort Fangzheng Liu
collection DOAJ
description An electrochemical reactions coupled multi-physics model is developed and applied to elucidate overall performance and thermal stress distributed in solid oxide electrolysis cells (SOECs) with graded fuel electrodes. Extending the conventional fuel electrode, the effects of various graded parameters are investigated and discussed in terms of porosity, pore size, and material composition, with the goal of identifying characteristics of the hydrogen production rate and maximum thermal stress. The results show that the application of the graded parameters is able to optimize the gas distribution and to improve reaction kinetics, avoiding local overheating. The generated hydrogen molar fraction is enhanced by 15.6% while the maximum thermal stress is decreased by 5.0% if the graded parameters are applied, while changing the material composition may increase the thermal stress under the same circumstances. These explorations elucidate the complex role of the graded fuel electrodes on the electrolysis and thermomechanical properties of SOECs.
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series Energies
spelling doaj-art-aee890de82c94313b511258ca6f076c12025-08-20T02:23:04ZengMDPI AGEnergies1996-10732025-05-011811279010.3390/en18112790Evaluation of Thermal Stress and Performance for Solid Oxide Electrolysis Cells Employing Graded Fuel ElectrodesFangzheng Liu0Liusheng Xiao1Ruidong Zhou2Qi Liu3Jinliang Yuan4Faculty of Maritime and Transportation, Ningbo University, Ningbo 315832, ChinaFaculty of Maritime and Transportation, Ningbo University, Ningbo 315832, ChinaFaculty of Maritime and Transportation, Ningbo University, Ningbo 315832, ChinaFaculty of Maritime and Transportation, Ningbo University, Ningbo 315832, ChinaFaculty of Maritime and Transportation, Ningbo University, Ningbo 315832, ChinaAn electrochemical reactions coupled multi-physics model is developed and applied to elucidate overall performance and thermal stress distributed in solid oxide electrolysis cells (SOECs) with graded fuel electrodes. Extending the conventional fuel electrode, the effects of various graded parameters are investigated and discussed in terms of porosity, pore size, and material composition, with the goal of identifying characteristics of the hydrogen production rate and maximum thermal stress. The results show that the application of the graded parameters is able to optimize the gas distribution and to improve reaction kinetics, avoiding local overheating. The generated hydrogen molar fraction is enhanced by 15.6% while the maximum thermal stress is decreased by 5.0% if the graded parameters are applied, while changing the material composition may increase the thermal stress under the same circumstances. These explorations elucidate the complex role of the graded fuel electrodes on the electrolysis and thermomechanical properties of SOECs.https://www.mdpi.com/1996-1073/18/11/2790solid oxide electrolysis cellgraded structurefuel electrodethermal stressmodel and simulation
spellingShingle Fangzheng Liu
Liusheng Xiao
Ruidong Zhou
Qi Liu
Jinliang Yuan
Evaluation of Thermal Stress and Performance for Solid Oxide Electrolysis Cells Employing Graded Fuel Electrodes
Energies
solid oxide electrolysis cell
graded structure
fuel electrode
thermal stress
model and simulation
title Evaluation of Thermal Stress and Performance for Solid Oxide Electrolysis Cells Employing Graded Fuel Electrodes
title_full Evaluation of Thermal Stress and Performance for Solid Oxide Electrolysis Cells Employing Graded Fuel Electrodes
title_fullStr Evaluation of Thermal Stress and Performance for Solid Oxide Electrolysis Cells Employing Graded Fuel Electrodes
title_full_unstemmed Evaluation of Thermal Stress and Performance for Solid Oxide Electrolysis Cells Employing Graded Fuel Electrodes
title_short Evaluation of Thermal Stress and Performance for Solid Oxide Electrolysis Cells Employing Graded Fuel Electrodes
title_sort evaluation of thermal stress and performance for solid oxide electrolysis cells employing graded fuel electrodes
topic solid oxide electrolysis cell
graded structure
fuel electrode
thermal stress
model and simulation
url https://www.mdpi.com/1996-1073/18/11/2790
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AT liushengxiao evaluationofthermalstressandperformanceforsolidoxideelectrolysiscellsemployinggradedfuelelectrodes
AT ruidongzhou evaluationofthermalstressandperformanceforsolidoxideelectrolysiscellsemployinggradedfuelelectrodes
AT qiliu evaluationofthermalstressandperformanceforsolidoxideelectrolysiscellsemployinggradedfuelelectrodes
AT jinliangyuan evaluationofthermalstressandperformanceforsolidoxideelectrolysiscellsemployinggradedfuelelectrodes