Voltammetric Behaviour and Analysis of Fluchloralin
The electrochemical reduction behavior of fluchloralin has been studied by D.C.polarography, differential pulse polarography, millicoulometry and controlled potential electrolysis in the universal buffers ranging from 2.0 to 12.0. Kinetic parameters were evaluated and a reduction mechanism was propo...
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| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
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Wiley
2010-01-01
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| Series: | E-Journal of Chemistry |
| Online Access: | http://dx.doi.org/10.1155/2010/419705 |
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| author | K. Balaji C. Sridevi N. Ananda Kumar Reddy K. Mohana Muni Sidda Reddy C. Suresh Reddy |
| author_facet | K. Balaji C. Sridevi N. Ananda Kumar Reddy K. Mohana Muni Sidda Reddy C. Suresh Reddy |
| author_sort | K. Balaji |
| collection | DOAJ |
| description | The electrochemical reduction behavior of fluchloralin has been studied by D.C.polarography, differential pulse polarography, millicoulometry and controlled potential electrolysis in the universal buffers ranging from 2.0 to 12.0. Kinetic parameters were evaluated and a reduction mechanism was proposed. A simple and rapid differential pulse polarographic method has been developed for the determination of fluchloralin in formulations, grains, soils and spiked water samples. The lower detection limit was found to be 1.5×10-8 M. Both the standard addition and calibration methods were used for the analytical measurements. |
| format | Article |
| id | doaj-art-ac7a84f1a11f40ed89a29f0486c13e9e |
| institution | Kabale University |
| issn | 0973-4945 2090-9810 |
| language | English |
| publishDate | 2010-01-01 |
| publisher | Wiley |
| record_format | Article |
| series | E-Journal of Chemistry |
| spelling | doaj-art-ac7a84f1a11f40ed89a29f0486c13e9e2025-02-03T06:48:17ZengWileyE-Journal of Chemistry0973-49452090-98102010-01-01741605161110.1155/2010/419705Voltammetric Behaviour and Analysis of FluchloralinK. Balaji0C. Sridevi1N. Ananda Kumar Reddy2K. Mohana Muni Sidda Reddy3C. Suresh Reddy4Department of Chemistry, S.V.University, Tirupati, IndiaDepartment of Chemistry, S.P.W. Degree and PG College, Tirupati, IndiaDepartment of Chemistry, S.V. Degree and PG College, Kadapa, IndiaDepartment of Chemistry, S.V. Arts College, Tirupati, IndiaDepartment of Chemistry, S.V.University, Tirupati, IndiaThe electrochemical reduction behavior of fluchloralin has been studied by D.C.polarography, differential pulse polarography, millicoulometry and controlled potential electrolysis in the universal buffers ranging from 2.0 to 12.0. Kinetic parameters were evaluated and a reduction mechanism was proposed. A simple and rapid differential pulse polarographic method has been developed for the determination of fluchloralin in formulations, grains, soils and spiked water samples. The lower detection limit was found to be 1.5×10-8 M. Both the standard addition and calibration methods were used for the analytical measurements.http://dx.doi.org/10.1155/2010/419705 |
| spellingShingle | K. Balaji C. Sridevi N. Ananda Kumar Reddy K. Mohana Muni Sidda Reddy C. Suresh Reddy Voltammetric Behaviour and Analysis of Fluchloralin E-Journal of Chemistry |
| title | Voltammetric Behaviour and Analysis of Fluchloralin |
| title_full | Voltammetric Behaviour and Analysis of Fluchloralin |
| title_fullStr | Voltammetric Behaviour and Analysis of Fluchloralin |
| title_full_unstemmed | Voltammetric Behaviour and Analysis of Fluchloralin |
| title_short | Voltammetric Behaviour and Analysis of Fluchloralin |
| title_sort | voltammetric behaviour and analysis of fluchloralin |
| url | http://dx.doi.org/10.1155/2010/419705 |
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