Arsine, Stibine and Phosphine Derivatives of [Fe<sub>2</sub>(CO)<sub>6</sub>(μ-bdt)] (bdt = Benzenedithiolate): Syntheses, Structures and Spectroscopic and Electrocatalytic Studies

Arsine, Stibine and Phosphine Derivatives of [Fe<sub>2</sub>(CO)<sub>6</sub>(μ-bdt)] (bdt = Benzenedithiolate): Syntheses, Structures and Spectroscopic and Electrocatalytic Studies

The reactivity of the benzenedithiolate (bdt)-bridged complex [Fe<sub>2</sub>(CO)<sub>6</sub>(µ-bdt)] with arsine, stibine and phosphine ligands has been studied. The new mono- and disubstituted complexes [Fe<sub>2</sub>(CO)<sub>5</sub>(EPh<sub>3...

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Bibliographic Details
Main Authors: Ahibur Rahaman, Ummey Kulsume, Fakir R. Alam, Matti Haukka, Shishir Ghosh, Graeme Hogarth, Ebbe Nordlander, Shariff E. Kabir
Format: Article
Language:English
Published: MDPI AG 2025-02-01
Series:Inorganics
Subjects:
diiron-dithiolate complex
CO substitution
triphenylarsine
triphenylstibine
proton reduction
Online Access:https://www.mdpi.com/2304-6740/13/2/63
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