Synthesis and Characterization of Some New Thermal Stable Polymers - Polymerization of N-[4-N´ -(Benzylamino-carbonyl)phenyl]maleimide
This article describes the synthesis and characterization of homopolymer (H-BCPM) of N-[4-N'-(benzylamino-carbonyl) phenyl] maleimide (N-BACPMI) and copolymer (C-BCPM) of N-BACPMI with n-butyl acrylate (BA). The new monomer was synthesized from p-aminobenzoic acid, maleic anhydride and benzylam...
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| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
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Wiley
2007-01-01
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| Series: | E-Journal of Chemistry |
| Online Access: | http://dx.doi.org/10.1155/2007/857326 |
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| author | B. L. Hiran Jyoti Chadhary S. N. Paliwal Suresh Meena P. R. Chaudhary |
| author_facet | B. L. Hiran Jyoti Chadhary S. N. Paliwal Suresh Meena P. R. Chaudhary |
| author_sort | B. L. Hiran |
| collection | DOAJ |
| description | This article describes the synthesis and characterization of homopolymer (H-BCPM) of N-[4-N'-(benzylamino-carbonyl) phenyl] maleimide (N-BACPMI) and copolymer (C-BCPM) of N-BACPMI with n-butyl acrylate (BA). The new monomer was synthesized from p-aminobenzoic acid, maleic anhydride and benzylamine. The homopolymerization of N-BACPMI is initiated by free radical using AIBN in THF solvent at 65°C. Radical copolymerization of N-BACPMI with BA, initiated by AIBN, was performed in THF solvent using equimolar amount. Effect of the different free radical initiator AIBN, BPO and solvents p-Dioxane, THF, DMF and DMSO was studied. Homopolymer and Copolymer were characterized by intrinsic viscosity, solubility test, FT-IR, 1H-NMR spectral analysis and elemental analysis. Thermal behaviour was studied by Thermo gravimetric analysis. |
| format | Article |
| id | doaj-art-abf46a022ad4421faf4efe04b8acbf3b |
| institution | Kabale University |
| issn | 0973-4945 2090-9810 |
| language | English |
| publishDate | 2007-01-01 |
| publisher | Wiley |
| record_format | Article |
| series | E-Journal of Chemistry |
| spelling | doaj-art-abf46a022ad4421faf4efe04b8acbf3b2025-02-03T05:45:12ZengWileyE-Journal of Chemistry0973-49452090-98102007-01-014222223110.1155/2007/857326Synthesis and Characterization of Some New Thermal Stable Polymers - Polymerization of N-[4-N´ -(Benzylamino-carbonyl)phenyl]maleimideB. L. Hiran0Jyoti Chadhary1S. N. Paliwal2Suresh Meena3P. R. Chaudhary4Chemical Kinetics and Polymer Research Laboratory, Department of Chemistry, M. L. S. University, Udaipur (Raj.) 313 001., IndiaChemical Kinetics and Polymer Research Laboratory, Department of Chemistry, M. L. S. University, Udaipur (Raj.) 313 001., IndiaChemical Kinetics and Polymer Research Laboratory, Department of Chemistry, M. L. S. University, Udaipur (Raj.) 313 001., IndiaChemical Kinetics and Polymer Research Laboratory, Department of Chemistry, M. L. S. University, Udaipur (Raj.) 313 001., IndiaChemical Kinetics and Polymer Research Laboratory, Department of Chemistry, M. L. S. University, Udaipur (Raj.) 313 001., IndiaThis article describes the synthesis and characterization of homopolymer (H-BCPM) of N-[4-N'-(benzylamino-carbonyl) phenyl] maleimide (N-BACPMI) and copolymer (C-BCPM) of N-BACPMI with n-butyl acrylate (BA). The new monomer was synthesized from p-aminobenzoic acid, maleic anhydride and benzylamine. The homopolymerization of N-BACPMI is initiated by free radical using AIBN in THF solvent at 65°C. Radical copolymerization of N-BACPMI with BA, initiated by AIBN, was performed in THF solvent using equimolar amount. Effect of the different free radical initiator AIBN, BPO and solvents p-Dioxane, THF, DMF and DMSO was studied. Homopolymer and Copolymer were characterized by intrinsic viscosity, solubility test, FT-IR, 1H-NMR spectral analysis and elemental analysis. Thermal behaviour was studied by Thermo gravimetric analysis.http://dx.doi.org/10.1155/2007/857326 |
| spellingShingle | B. L. Hiran Jyoti Chadhary S. N. Paliwal Suresh Meena P. R. Chaudhary Synthesis and Characterization of Some New Thermal Stable Polymers - Polymerization of N-[4-N´ -(Benzylamino-carbonyl)phenyl]maleimide E-Journal of Chemistry |
| title | Synthesis and Characterization of Some New Thermal Stable Polymers - Polymerization of N-[4-N´ -(Benzylamino-carbonyl)phenyl]maleimide |
| title_full | Synthesis and Characterization of Some New Thermal Stable Polymers - Polymerization of N-[4-N´ -(Benzylamino-carbonyl)phenyl]maleimide |
| title_fullStr | Synthesis and Characterization of Some New Thermal Stable Polymers - Polymerization of N-[4-N´ -(Benzylamino-carbonyl)phenyl]maleimide |
| title_full_unstemmed | Synthesis and Characterization of Some New Thermal Stable Polymers - Polymerization of N-[4-N´ -(Benzylamino-carbonyl)phenyl]maleimide |
| title_short | Synthesis and Characterization of Some New Thermal Stable Polymers - Polymerization of N-[4-N´ -(Benzylamino-carbonyl)phenyl]maleimide |
| title_sort | synthesis and characterization of some new thermal stable polymers polymerization of n 4 n´ benzylamino carbonyl phenyl maleimide |
| url | http://dx.doi.org/10.1155/2007/857326 |
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