Unexpected stability of the iron(II) complex by an asymmetrical Schiff base from Fe(III): structure, magnetic and Mössbauer investigations

The asymmetric Schiff base prepared in situ from ethylenediamine and pyridine-2-carboxaldehyde reacts with Fe(ClO4)3·6H2O to form the Fe(II) complex [FeL2](ClO4)2 with L = N,N-diethyl-N′-(pyridin-2-yl)methylene)ethane-1,2-diamine, where the Fe(III) starting material has been unexpectedly reduced to...

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Bibliographic Details
Main Authors: Dawit Tesfaye, Mamo Gebrezgiabher, Jonas Braun, Taju Sani, Sebastien Diliberto, Pascal Boulet, Nandakumar Kalarikkal, Christopher E. Anson, Annie K. Powell, Madhu Thomas
Format: Article
Language:English
Published: The Royal Society 2025-01-01
Series:Royal Society Open Science
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Online Access:https://royalsocietypublishing.org/doi/10.1098/rsos.241334
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