Unexpected stability of the iron(II) complex by an asymmetrical Schiff base from Fe(III): structure, magnetic and Mössbauer investigations
The asymmetric Schiff base prepared in situ from ethylenediamine and pyridine-2-carboxaldehyde reacts with Fe(ClO4)3·6H2O to form the Fe(II) complex [FeL2](ClO4)2 with L = N,N-diethyl-N′-(pyridin-2-yl)methylene)ethane-1,2-diamine, where the Fe(III) starting material has been unexpectedly reduced to...
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Main Authors: | , , , , , , , , , |
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Format: | Article |
Language: | English |
Published: |
The Royal Society
2025-01-01
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Series: | Royal Society Open Science |
Subjects: | |
Online Access: | https://royalsocietypublishing.org/doi/10.1098/rsos.241334 |
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