Probe Molecule-Dependent Particle Density and its Effect on the Supercritical Gas Adsorption Isotherm of Nanoporous Cu Complex Crystals
Accurate particle densities of the Cu-based metal organic framework [Cu(4,4'-bipyridine) 2 (BF 4 ) 2 ] for He, N 2 and CH 4 molecules using the high-pressure buoyancy method have been determined. A smaller probe molecule gave a larger particle density (1.70 g/ml from He, 1.66 g/ml from N 2 , 1....
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Main Authors: | , , , , |
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Format: | Article |
Language: | English |
Published: |
SAGE Publishing
2006-09-01
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Series: | Adsorption Science & Technology |
Online Access: | https://doi.org/10.1260/026361706780810258 |
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