Engineered Multifunctional Fluorinated Film Based on Semicontinuous Emulsion Polymerization Using Polymerizable Quaternary Ammonium Emulsifiers
Along with society’s progress, high-quality coatings are widely used. Although fluorinated polymers were successfully prepared by semicontinuous emulsion polymerization with surfactants, chlorotrifluoroethylene (CTFE), and acrylate monomers, the optimization collocation of surfactants still has room...
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| Main Authors: | , , , , , , |
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| Format: | Article |
| Language: | English |
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Wiley
2018-01-01
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| Series: | International Journal of Polymer Science |
| Online Access: | http://dx.doi.org/10.1155/2018/5659137 |
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| author | Hongzhu Liu Lingnan Wang Minhuan Wang Chuan-Jin Hou Bin-bin Ye Zefeng Wang Jiming Bian |
| author_facet | Hongzhu Liu Lingnan Wang Minhuan Wang Chuan-Jin Hou Bin-bin Ye Zefeng Wang Jiming Bian |
| author_sort | Hongzhu Liu |
| collection | DOAJ |
| description | Along with society’s progress, high-quality coatings are widely used. Although fluorinated polymers were successfully prepared by semicontinuous emulsion polymerization with surfactants, chlorotrifluoroethylene (CTFE), and acrylate monomers, the optimization collocation of surfactants still has room for improvement. The traditional emulsifiers are physically absorbed onto the surface of latex particles. The latex film generated by latex particles is unstable in water, which limits its application. Herein, a novel series of cationic quaternary ammonium polymerizable surfactant was selected because it can react with CTFE and acrylate monomers and can become a part of the polymers. We also studied the effects of emulsifier type on resultant emulsion properties. In addition, wonderful weatherability, water resistance, and antibacterial and antifouling of the multifunctional fluorinated films were observed, which would open up a bright future for coating industries. |
| format | Article |
| id | doaj-art-a98cfbb8c24243e0ab754620aa30c16d |
| institution | Kabale University |
| issn | 1687-9422 1687-9430 |
| language | English |
| publishDate | 2018-01-01 |
| publisher | Wiley |
| record_format | Article |
| series | International Journal of Polymer Science |
| spelling | doaj-art-a98cfbb8c24243e0ab754620aa30c16d2025-02-03T01:28:48ZengWileyInternational Journal of Polymer Science1687-94221687-94302018-01-01201810.1155/2018/56591375659137Engineered Multifunctional Fluorinated Film Based on Semicontinuous Emulsion Polymerization Using Polymerizable Quaternary Ammonium EmulsifiersHongzhu Liu0Lingnan Wang1Minhuan Wang2Chuan-Jin Hou3Bin-bin Ye4Zefeng Wang5Jiming Bian6Key Laboratory of Materials Modification by Laser, Ion and Electron Beams (Ministry of Education), School of Physics, Dalian University of Technology, Dalian 116024, ChinaSchool of Ophthalmology and Optometry, Eye Hospital, School of Biomedical Engineering, Wenzhou Medical University, Wenzhou 325027, ChinaKey Laboratory of Materials Modification by Laser, Ion and Electron Beams (Ministry of Education), School of Physics, Dalian University of Technology, Dalian 116024, ChinaPost-Doctoral Research Station, Dalian Zhenbang Fluorocarbon Paint Stock Co., Ltd., Dalian 116036, ChinaSchool of Ophthalmology and Optometry, Eye Hospital, School of Biomedical Engineering, Wenzhou Medical University, Wenzhou 325027, ChinaSchool of Ophthalmology and Optometry, Eye Hospital, School of Biomedical Engineering, Wenzhou Medical University, Wenzhou 325027, ChinaKey Laboratory of Materials Modification by Laser, Ion and Electron Beams (Ministry of Education), School of Physics, Dalian University of Technology, Dalian 116024, ChinaAlong with society’s progress, high-quality coatings are widely used. Although fluorinated polymers were successfully prepared by semicontinuous emulsion polymerization with surfactants, chlorotrifluoroethylene (CTFE), and acrylate monomers, the optimization collocation of surfactants still has room for improvement. The traditional emulsifiers are physically absorbed onto the surface of latex particles. The latex film generated by latex particles is unstable in water, which limits its application. Herein, a novel series of cationic quaternary ammonium polymerizable surfactant was selected because it can react with CTFE and acrylate monomers and can become a part of the polymers. We also studied the effects of emulsifier type on resultant emulsion properties. In addition, wonderful weatherability, water resistance, and antibacterial and antifouling of the multifunctional fluorinated films were observed, which would open up a bright future for coating industries.http://dx.doi.org/10.1155/2018/5659137 |
| spellingShingle | Hongzhu Liu Lingnan Wang Minhuan Wang Chuan-Jin Hou Bin-bin Ye Zefeng Wang Jiming Bian Engineered Multifunctional Fluorinated Film Based on Semicontinuous Emulsion Polymerization Using Polymerizable Quaternary Ammonium Emulsifiers International Journal of Polymer Science |
| title | Engineered Multifunctional Fluorinated Film Based on Semicontinuous Emulsion Polymerization Using Polymerizable Quaternary Ammonium Emulsifiers |
| title_full | Engineered Multifunctional Fluorinated Film Based on Semicontinuous Emulsion Polymerization Using Polymerizable Quaternary Ammonium Emulsifiers |
| title_fullStr | Engineered Multifunctional Fluorinated Film Based on Semicontinuous Emulsion Polymerization Using Polymerizable Quaternary Ammonium Emulsifiers |
| title_full_unstemmed | Engineered Multifunctional Fluorinated Film Based on Semicontinuous Emulsion Polymerization Using Polymerizable Quaternary Ammonium Emulsifiers |
| title_short | Engineered Multifunctional Fluorinated Film Based on Semicontinuous Emulsion Polymerization Using Polymerizable Quaternary Ammonium Emulsifiers |
| title_sort | engineered multifunctional fluorinated film based on semicontinuous emulsion polymerization using polymerizable quaternary ammonium emulsifiers |
| url | http://dx.doi.org/10.1155/2018/5659137 |
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