catena-Poly[[diphenyltin(IV)]-di-μ-isothiocyanato]: an unprecedented layered coordination polymer resulting from bridging κ2N:S thiocyanato ligands

catena-Poly[[diphenyltin(IV)]-di-μ-isothiocyanato]: an unprecedented layered coordination polymer resulting from bridging κ2N:S thiocyanato ligands

In the title compound, diphenyltin(IV) diisothiocyanate, [Sn(NCS)2(C6H5)2]n or Ph2Sn(NCS)2, comparatively long tin–nitrogen and short tin–sulfur bonds prove that the ambidentate isothiocyanate ion acts as a bridge between two neighboring, octahedrally coordinated tin atoms. As a result, the molecule...

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Bibliographic Details
Main Authors: Ann-Kathrin Pancratz, Anne Kamrowski, Hans Reuter
Format: Article
Language:English
Published: International Union of Crystallography 2024-11-01
Series:IUCrData
Subjects:
crystal structure
isothiocyanate
diphenyltin
layer structure
Online Access:https://journals.iucr.org/paper?S2414314624010939
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