Staminate Flower of Cocos Nucifera as Green Inhibitor for Mild Steel in HCl Medium

Corrosion control methods, especially the use of inhibitors, have gained monumental importance in the present scenario of expunging corrosion and the quest for eco-friendly reasons continues. To arrive at an inexpensive non-toxic, eco-friendly inhibitor formulations the present study on the use of S...

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Main Authors: R. Rajalakshmi, A. S. Safina
Format: Article
Language:English
Published: Wiley 2012-01-01
Series:E-Journal of Chemistry
Online Access:http://dx.doi.org/10.1155/2012/138463
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author R. Rajalakshmi
A. S. Safina
author_facet R. Rajalakshmi
A. S. Safina
author_sort R. Rajalakshmi
collection DOAJ
description Corrosion control methods, especially the use of inhibitors, have gained monumental importance in the present scenario of expunging corrosion and the quest for eco-friendly reasons continues. To arrive at an inexpensive non-toxic, eco-friendly inhibitor formulations the present study on the use of Staminate Flower extract of Cocos Nucifera has been carried out by the classical weight loss measurements and electrochemical polarization measurements. The acid extract could bring out a maximum of 97.3% inhibition of mild steel corrosion in 1M HCl. Thermodynamic parameters of the corrosion process were calculated from temperature study. The adsorptive behaviour of Staminate Flower extract in acid solution may be approximated both by Langmuir and Temkin type isotherms. The results obtained by Tafel, Linear polarization resistance, and impedance spectroscopy have been correlated with the classical weight loss measurements. Values of Tafel constant ba and bc confirmed that the Staminate Flower extract acts like mixed type inhibitor. Examination of the surface of the metal in the presence of the inhibitor confirmed the deposition of inhibitor on the metal surface. The Staminate Flower extract in HCl medium efficiently inhibits the corrosion and proved to be zero cost inhibitor, eco-friendly, non-toxic, and highly economical.
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spelling doaj-art-a7a7aa425dfc4cbabf778a57bdc4ad3f2025-02-03T05:53:54ZengWileyE-Journal of Chemistry0973-49452090-98102012-01-01931632164410.1155/2012/138463Staminate Flower of Cocos Nucifera as Green Inhibitor for Mild Steel in HCl MediumR. Rajalakshmi0A. S. Safina1Department of Chemistry, Avinashilingam University for Women, Coimbatore, IndiaDepartment of Chemistry, V.L.B. Janakiammal College of Engg. & Tech, Coimbatore, IndiaCorrosion control methods, especially the use of inhibitors, have gained monumental importance in the present scenario of expunging corrosion and the quest for eco-friendly reasons continues. To arrive at an inexpensive non-toxic, eco-friendly inhibitor formulations the present study on the use of Staminate Flower extract of Cocos Nucifera has been carried out by the classical weight loss measurements and electrochemical polarization measurements. The acid extract could bring out a maximum of 97.3% inhibition of mild steel corrosion in 1M HCl. Thermodynamic parameters of the corrosion process were calculated from temperature study. The adsorptive behaviour of Staminate Flower extract in acid solution may be approximated both by Langmuir and Temkin type isotherms. The results obtained by Tafel, Linear polarization resistance, and impedance spectroscopy have been correlated with the classical weight loss measurements. Values of Tafel constant ba and bc confirmed that the Staminate Flower extract acts like mixed type inhibitor. Examination of the surface of the metal in the presence of the inhibitor confirmed the deposition of inhibitor on the metal surface. The Staminate Flower extract in HCl medium efficiently inhibits the corrosion and proved to be zero cost inhibitor, eco-friendly, non-toxic, and highly economical.http://dx.doi.org/10.1155/2012/138463
spellingShingle R. Rajalakshmi
A. S. Safina
Staminate Flower of Cocos Nucifera as Green Inhibitor for Mild Steel in HCl Medium
E-Journal of Chemistry
title Staminate Flower of Cocos Nucifera as Green Inhibitor for Mild Steel in HCl Medium
title_full Staminate Flower of Cocos Nucifera as Green Inhibitor for Mild Steel in HCl Medium
title_fullStr Staminate Flower of Cocos Nucifera as Green Inhibitor for Mild Steel in HCl Medium
title_full_unstemmed Staminate Flower of Cocos Nucifera as Green Inhibitor for Mild Steel in HCl Medium
title_short Staminate Flower of Cocos Nucifera as Green Inhibitor for Mild Steel in HCl Medium
title_sort staminate flower of cocos nucifera as green inhibitor for mild steel in hcl medium
url http://dx.doi.org/10.1155/2012/138463
work_keys_str_mv AT rrajalakshmi staminateflowerofcocosnuciferaasgreeninhibitorformildsteelinhclmedium
AT assafina staminateflowerofcocosnuciferaasgreeninhibitorformildsteelinhclmedium