Effect of binary basicity on chromium occurrence in stainless steel slag
Comprehensive utilization of stainless-steel slag (SSS) is restrained due to the risk of Cr6+ leaching. Based on the studying the microstructure of synthetic slag (SS) containing Cr2O3 with XRD, SEM-EDS, and Image pro, the effect of binary basicity on the chromium occurrence in SSS was investigated....
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University of Belgrade, Technical Faculty, Bor
2022-01-01
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Series: | Journal of Mining and Metallurgy. Section B: Metallurgy |
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Online Access: | http://www.doiserbia.nb.rs/img/doi/1450-5339/2022/1450-53392100043Z.pdf |
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author | Zeng Q. Li J.-L. Ma G.-J. Zhu H.-Y. |
author_facet | Zeng Q. Li J.-L. Ma G.-J. Zhu H.-Y. |
author_sort | Zeng Q. |
collection | DOAJ |
description | Comprehensive utilization of stainless-steel slag (SSS) is restrained due to the risk of Cr6+ leaching. Based on the studying the microstructure of synthetic slag (SS) containing Cr2O3 with XRD, SEM-EDS, and Image pro, the effect of binary basicity on the chromium occurrence in SSS was investigated. The results indicated that the binary basicity had a significant impact on the properties of spinel crystals. There was a positive correlation between the calcium content in spinel crystals and the SS basicity. The size of spinel crystals varied from large to small and the precipitation occurrence changed with the basicity increase. Furthermore, the chromium occurrences changed with the basicity. The chromium was produced in spinel crystals at lower basicity, but as the basicity increased to 3.0, the chromium precipitated as calcium chromate. In view of the relationship between the chromium leaching behavior and its occurrence, increasing basicity raised the Cr6+ leaching. |
format | Article |
id | doaj-art-a56c94b7934044f3b861a270545a0abe |
institution | Kabale University |
issn | 1450-5339 2217-7175 |
language | English |
publishDate | 2022-01-01 |
publisher | University of Belgrade, Technical Faculty, Bor |
record_format | Article |
series | Journal of Mining and Metallurgy. Section B: Metallurgy |
spelling | doaj-art-a56c94b7934044f3b861a270545a0abe2025-02-02T13:17:09ZengUniversity of Belgrade, Technical Faculty, BorJournal of Mining and Metallurgy. Section B: Metallurgy1450-53392217-71752022-01-01581111810.2298/JMMB210304043Z1450-53392100043ZEffect of binary basicity on chromium occurrence in stainless steel slagZeng Q.0Li J.-L.1Ma G.-J.2Zhu H.-Y.3The State Key Laboratory of Refractories and Metallurgy, Wuhan University of Science and Technology, Wuhan, ChinaThe State Key Laboratory of Refractories and Metallurgy, Wuhan University of Science and Technology, Wuhan, China + Hubei Provincial Key Laboratory for New Processes of Ironmaking and Steelmaking, Wuhan University of Science and Technology, Wuhan, China + Key Laboratory for Ferrous Metallurgy and Resources Utilization of Ministry of Education, Wuhan University of Science and Technology, Wuhan, ChinaThe State Key Laboratory of Refractories and Metallurgy, Wuhan University of Science and Technology, Wuhan, ChinaThe State Key Laboratory of Refractories and Metallurgy, Wuhan University of Science and Technology, Wuhan, ChinaComprehensive utilization of stainless-steel slag (SSS) is restrained due to the risk of Cr6+ leaching. Based on the studying the microstructure of synthetic slag (SS) containing Cr2O3 with XRD, SEM-EDS, and Image pro, the effect of binary basicity on the chromium occurrence in SSS was investigated. The results indicated that the binary basicity had a significant impact on the properties of spinel crystals. There was a positive correlation between the calcium content in spinel crystals and the SS basicity. The size of spinel crystals varied from large to small and the precipitation occurrence changed with the basicity increase. Furthermore, the chromium occurrences changed with the basicity. The chromium was produced in spinel crystals at lower basicity, but as the basicity increased to 3.0, the chromium precipitated as calcium chromate. In view of the relationship between the chromium leaching behavior and its occurrence, increasing basicity raised the Cr6+ leaching.http://www.doiserbia.nb.rs/img/doi/1450-5339/2022/1450-53392100043Z.pdfstainless steel slag (sss)hexavalent chromiumspinel crystalsbinary basicity |
spellingShingle | Zeng Q. Li J.-L. Ma G.-J. Zhu H.-Y. Effect of binary basicity on chromium occurrence in stainless steel slag Journal of Mining and Metallurgy. Section B: Metallurgy stainless steel slag (sss) hexavalent chromium spinel crystals binary basicity |
title | Effect of binary basicity on chromium occurrence in stainless steel slag |
title_full | Effect of binary basicity on chromium occurrence in stainless steel slag |
title_fullStr | Effect of binary basicity on chromium occurrence in stainless steel slag |
title_full_unstemmed | Effect of binary basicity on chromium occurrence in stainless steel slag |
title_short | Effect of binary basicity on chromium occurrence in stainless steel slag |
title_sort | effect of binary basicity on chromium occurrence in stainless steel slag |
topic | stainless steel slag (sss) hexavalent chromium spinel crystals binary basicity |
url | http://www.doiserbia.nb.rs/img/doi/1450-5339/2022/1450-53392100043Z.pdf |
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