Effect of binary basicity on chromium occurrence in stainless steel slag

Comprehensive utilization of stainless-steel slag (SSS) is restrained due to the risk of Cr6+ leaching. Based on the studying the microstructure of synthetic slag (SS) containing Cr2O3 with XRD, SEM-EDS, and Image pro, the effect of binary basicity on the chromium occurrence in SSS was investigated....

Full description

Saved in:
Bibliographic Details
Main Authors: Zeng Q., Li J.-L., Ma G.-J., Zhu H.-Y.
Format: Article
Language:English
Published: University of Belgrade, Technical Faculty, Bor 2022-01-01
Series:Journal of Mining and Metallurgy. Section B: Metallurgy
Subjects:
Online Access:http://www.doiserbia.nb.rs/img/doi/1450-5339/2022/1450-53392100043Z.pdf
Tags: Add Tag
No Tags, Be the first to tag this record!
_version_ 1832571121074962432
author Zeng Q.
Li J.-L.
Ma G.-J.
Zhu H.-Y.
author_facet Zeng Q.
Li J.-L.
Ma G.-J.
Zhu H.-Y.
author_sort Zeng Q.
collection DOAJ
description Comprehensive utilization of stainless-steel slag (SSS) is restrained due to the risk of Cr6+ leaching. Based on the studying the microstructure of synthetic slag (SS) containing Cr2O3 with XRD, SEM-EDS, and Image pro, the effect of binary basicity on the chromium occurrence in SSS was investigated. The results indicated that the binary basicity had a significant impact on the properties of spinel crystals. There was a positive correlation between the calcium content in spinel crystals and the SS basicity. The size of spinel crystals varied from large to small and the precipitation occurrence changed with the basicity increase. Furthermore, the chromium occurrences changed with the basicity. The chromium was produced in spinel crystals at lower basicity, but as the basicity increased to 3.0, the chromium precipitated as calcium chromate. In view of the relationship between the chromium leaching behavior and its occurrence, increasing basicity raised the Cr6+ leaching.
format Article
id doaj-art-a56c94b7934044f3b861a270545a0abe
institution Kabale University
issn 1450-5339
2217-7175
language English
publishDate 2022-01-01
publisher University of Belgrade, Technical Faculty, Bor
record_format Article
series Journal of Mining and Metallurgy. Section B: Metallurgy
spelling doaj-art-a56c94b7934044f3b861a270545a0abe2025-02-02T13:17:09ZengUniversity of Belgrade, Technical Faculty, BorJournal of Mining and Metallurgy. Section B: Metallurgy1450-53392217-71752022-01-01581111810.2298/JMMB210304043Z1450-53392100043ZEffect of binary basicity on chromium occurrence in stainless steel slagZeng Q.0Li J.-L.1Ma G.-J.2Zhu H.-Y.3The State Key Laboratory of Refractories and Metallurgy, Wuhan University of Science and Technology, Wuhan, ChinaThe State Key Laboratory of Refractories and Metallurgy, Wuhan University of Science and Technology, Wuhan, China + Hubei Provincial Key Laboratory for New Processes of Ironmaking and Steelmaking, Wuhan University of Science and Technology, Wuhan, China + Key Laboratory for Ferrous Metallurgy and Resources Utilization of Ministry of Education, Wuhan University of Science and Technology, Wuhan, ChinaThe State Key Laboratory of Refractories and Metallurgy, Wuhan University of Science and Technology, Wuhan, ChinaThe State Key Laboratory of Refractories and Metallurgy, Wuhan University of Science and Technology, Wuhan, ChinaComprehensive utilization of stainless-steel slag (SSS) is restrained due to the risk of Cr6+ leaching. Based on the studying the microstructure of synthetic slag (SS) containing Cr2O3 with XRD, SEM-EDS, and Image pro, the effect of binary basicity on the chromium occurrence in SSS was investigated. The results indicated that the binary basicity had a significant impact on the properties of spinel crystals. There was a positive correlation between the calcium content in spinel crystals and the SS basicity. The size of spinel crystals varied from large to small and the precipitation occurrence changed with the basicity increase. Furthermore, the chromium occurrences changed with the basicity. The chromium was produced in spinel crystals at lower basicity, but as the basicity increased to 3.0, the chromium precipitated as calcium chromate. In view of the relationship between the chromium leaching behavior and its occurrence, increasing basicity raised the Cr6+ leaching.http://www.doiserbia.nb.rs/img/doi/1450-5339/2022/1450-53392100043Z.pdfstainless steel slag (sss)hexavalent chromiumspinel crystalsbinary basicity
spellingShingle Zeng Q.
Li J.-L.
Ma G.-J.
Zhu H.-Y.
Effect of binary basicity on chromium occurrence in stainless steel slag
Journal of Mining and Metallurgy. Section B: Metallurgy
stainless steel slag (sss)
hexavalent chromium
spinel crystals
binary basicity
title Effect of binary basicity on chromium occurrence in stainless steel slag
title_full Effect of binary basicity on chromium occurrence in stainless steel slag
title_fullStr Effect of binary basicity on chromium occurrence in stainless steel slag
title_full_unstemmed Effect of binary basicity on chromium occurrence in stainless steel slag
title_short Effect of binary basicity on chromium occurrence in stainless steel slag
title_sort effect of binary basicity on chromium occurrence in stainless steel slag
topic stainless steel slag (sss)
hexavalent chromium
spinel crystals
binary basicity
url http://www.doiserbia.nb.rs/img/doi/1450-5339/2022/1450-53392100043Z.pdf
work_keys_str_mv AT zengq effectofbinarybasicityonchromiumoccurrenceinstainlesssteelslag
AT lijl effectofbinarybasicityonchromiumoccurrenceinstainlesssteelslag
AT magj effectofbinarybasicityonchromiumoccurrenceinstainlesssteelslag
AT zhuhy effectofbinarybasicityonchromiumoccurrenceinstainlesssteelslag