Synthesis of a One-Dimensional Coordination Polymer of Nickel(II) Complex with a β-Oxodithioester Ligand
Bis-[methyl-1-hydroxy-1-cyclopentene-2-dithiocarboxylate-O,S]nickel(II) 1 was prepared starting from methyl 2-hydroxycyclopent-1-encarbodithioate ligand (CPDT) and Ni(II), and catena-[(μ2-4,4′-Bipyril)-bis-(methyl-2-hydroxy-1-cyclopentene-2-dithiocarboxylate-O,S)]nickel(ΙΙ) 2 was prepared in good yi...
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| Format: | Article |
| Language: | English |
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Wiley
2017-01-01
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| Series: | Journal of Chemistry |
| Online Access: | http://dx.doi.org/10.1155/2017/7623210 |
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| author | Ricardo Rosas-Reyes Yasmi Reyes-Ortega T. Jesus Morales-Juarez Virginia Gómez-Vidales Ivan García-Orozco |
| author_facet | Ricardo Rosas-Reyes Yasmi Reyes-Ortega T. Jesus Morales-Juarez Virginia Gómez-Vidales Ivan García-Orozco |
| author_sort | Ricardo Rosas-Reyes |
| collection | DOAJ |
| description | Bis-[methyl-1-hydroxy-1-cyclopentene-2-dithiocarboxylate-O,S]nickel(II) 1 was prepared starting from methyl 2-hydroxycyclopent-1-encarbodithioate ligand (CPDT) and Ni(II), and catena-[(μ2-4,4′-Bipyril)-bis-(methyl-2-hydroxy-1-cyclopentene-2-dithiocarboxylate-O,S)]nickel(ΙΙ) 2 was prepared in good yields from 1 plus 4,4′-bipyridyl (bpy) by shish-kebab methodology. The structure of 1 was confirmed by FTIR, elemental analysis, 1H NMR, UV–vis in chloroform solution and in solid, XPS, and PXRD. Compound 2 was characterized by FTIR, elemental analysis, UV–vis in chloroform solution, and in solid, XPS, PXRD, ESR, and solid state magnetization measurements. The structure of the polymer was established mostly by PXRD, ESR, and magnetization. |
| format | Article |
| id | doaj-art-a53865d1a2bc4edc9d7777165e461f92 |
| institution | Kabale University |
| issn | 2090-9063 2090-9071 |
| language | English |
| publishDate | 2017-01-01 |
| publisher | Wiley |
| record_format | Article |
| series | Journal of Chemistry |
| spelling | doaj-art-a53865d1a2bc4edc9d7777165e461f922025-02-03T06:07:04ZengWileyJournal of Chemistry2090-90632090-90712017-01-01201710.1155/2017/76232107623210Synthesis of a One-Dimensional Coordination Polymer of Nickel(II) Complex with a β-Oxodithioester LigandRicardo Rosas-Reyes0Yasmi Reyes-Ortega1T. Jesus Morales-Juarez2Virginia Gómez-Vidales3Ivan García-Orozco4Laboratorio de Investigación y Desarrollo de Materiales Avanzados (LIDMA), Facultad de Química, Universidad Autónoma del Estado de México, Carretera Toluca-Atlacomulco Km 14.5, Unidad San Cayetano, Toluca, MEX, MexicoCentro de Química, ICUAP, Benemérita Universidad Autónoma de Puebla, CU, 72570 Puebla, PUE, MexicoFacultad de Química, Universidad Autónoma del Estado de México, Paseo Colón esq. Paseo Tollocan s/n, 50120 Toluca, MEX, MexicoInstituto de Química, Universidad Nacional Autónoma de México, Circuito Interior, Ciudad Universitaria, Coyoacán, 01450 Mexico City, MexicoLaboratorio de Investigación y Desarrollo de Materiales Avanzados (LIDMA), Facultad de Química, Universidad Autónoma del Estado de México, Carretera Toluca-Atlacomulco Km 14.5, Unidad San Cayetano, Toluca, MEX, MexicoBis-[methyl-1-hydroxy-1-cyclopentene-2-dithiocarboxylate-O,S]nickel(II) 1 was prepared starting from methyl 2-hydroxycyclopent-1-encarbodithioate ligand (CPDT) and Ni(II), and catena-[(μ2-4,4′-Bipyril)-bis-(methyl-2-hydroxy-1-cyclopentene-2-dithiocarboxylate-O,S)]nickel(ΙΙ) 2 was prepared in good yields from 1 plus 4,4′-bipyridyl (bpy) by shish-kebab methodology. The structure of 1 was confirmed by FTIR, elemental analysis, 1H NMR, UV–vis in chloroform solution and in solid, XPS, and PXRD. Compound 2 was characterized by FTIR, elemental analysis, UV–vis in chloroform solution, and in solid, XPS, PXRD, ESR, and solid state magnetization measurements. The structure of the polymer was established mostly by PXRD, ESR, and magnetization.http://dx.doi.org/10.1155/2017/7623210 |
| spellingShingle | Ricardo Rosas-Reyes Yasmi Reyes-Ortega T. Jesus Morales-Juarez Virginia Gómez-Vidales Ivan García-Orozco Synthesis of a One-Dimensional Coordination Polymer of Nickel(II) Complex with a β-Oxodithioester Ligand Journal of Chemistry |
| title | Synthesis of a One-Dimensional Coordination Polymer of Nickel(II) Complex with a β-Oxodithioester Ligand |
| title_full | Synthesis of a One-Dimensional Coordination Polymer of Nickel(II) Complex with a β-Oxodithioester Ligand |
| title_fullStr | Synthesis of a One-Dimensional Coordination Polymer of Nickel(II) Complex with a β-Oxodithioester Ligand |
| title_full_unstemmed | Synthesis of a One-Dimensional Coordination Polymer of Nickel(II) Complex with a β-Oxodithioester Ligand |
| title_short | Synthesis of a One-Dimensional Coordination Polymer of Nickel(II) Complex with a β-Oxodithioester Ligand |
| title_sort | synthesis of a one dimensional coordination polymer of nickel ii complex with a β oxodithioester ligand |
| url | http://dx.doi.org/10.1155/2017/7623210 |
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