C-N vs. C-C Bond Photodissociation in N-(tert-butyldiphenylmethyl)aniline
The direct photolysis of the title aniline compound Ph2(Me3C) C-NHPh in acetonitrile with 248 nm laser light results in the dissociation of the C-N bond giving the corresponding (tert-Bu)diphenylmethyl radical 1a• and the anilino radical PhNH• detectable by ns-laser flash photolysis (LFP) and ESR sp...
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Main Authors: | , , |
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Format: | Article |
Language: | English |
Published: |
Wiley
2004-01-01
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Series: | International Journal of Photoenergy |
Online Access: | http://dx.doi.org/10.1155/S1110662X04000303 |
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