C-N vs. C-C Bond Photodissociation in N-(tert-butyldiphenylmethyl)aniline

The direct photolysis of the title aniline compound Ph2(Me3C) C-NHPh in acetonitrile with 248 nm laser light results in the dissociation of the C-N bond giving the corresponding (tert-Bu)diphenylmethyl radical 1a• and the anilino radical PhNH• detectable by ns-laser flash photolysis (LFP) and ESR sp...

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Bibliographic Details
Main Authors: Stylianos Garas, Michael G. Siskos, Antonios K. Zarkadis
Format: Article
Language:English
Published: Wiley 2004-01-01
Series:International Journal of Photoenergy
Online Access:http://dx.doi.org/10.1155/S1110662X04000303
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