Determination of the Parameters of Langmuir-Type Isotherms by the Frontal Analysis Method. Some Identification Aspects
The applicability of the classical frontal analysis method for the estimation of the parameters of various Langmuirian-type adsorption isotherms was examined. Elution profiles corresponding to several adsorption models were simulated using the equilibrium/dispersive model of chromatography. A noise...
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| Main Authors: | , |
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| Format: | Article |
| Language: | English |
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SAGE Publishing
2005-12-01
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| Series: | Adsorption Science & Technology |
| Online Access: | https://doi.org/10.1260/026361705775373260 |
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| _version_ | 1832544564931461120 |
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| author | Waldemar Nowicki Grażyna Nowicka |
| author_facet | Waldemar Nowicki Grażyna Nowicka |
| author_sort | Waldemar Nowicki |
| collection | DOAJ |
| description | The applicability of the classical frontal analysis method for the estimation of the parameters of various Langmuirian-type adsorption isotherms was examined. Elution profiles corresponding to several adsorption models were simulated using the equilibrium/dispersive model of chromatography. A noise sequence was added to the calculated profiles to simulate the detector error, following which the isotherm parameters were derived back from the generated chromatograms. The uncertainty of the estimates is discussed critically in terms of the standard deviations from the mean and real values of the parameters. |
| format | Article |
| id | doaj-art-a4874f2a81f54a3aaefee95b6cae50da |
| institution | Kabale University |
| issn | 0263-6174 2048-4038 |
| language | English |
| publishDate | 2005-12-01 |
| publisher | SAGE Publishing |
| record_format | Article |
| series | Adsorption Science & Technology |
| spelling | doaj-art-a4874f2a81f54a3aaefee95b6cae50da2025-02-03T10:08:10ZengSAGE PublishingAdsorption Science & Technology0263-61742048-40382005-12-012310.1260/026361705775373260Determination of the Parameters of Langmuir-Type Isotherms by the Frontal Analysis Method. Some Identification AspectsWaldemar NowickiGrażyna NowickaThe applicability of the classical frontal analysis method for the estimation of the parameters of various Langmuirian-type adsorption isotherms was examined. Elution profiles corresponding to several adsorption models were simulated using the equilibrium/dispersive model of chromatography. A noise sequence was added to the calculated profiles to simulate the detector error, following which the isotherm parameters were derived back from the generated chromatograms. The uncertainty of the estimates is discussed critically in terms of the standard deviations from the mean and real values of the parameters.https://doi.org/10.1260/026361705775373260 |
| spellingShingle | Waldemar Nowicki Grażyna Nowicka Determination of the Parameters of Langmuir-Type Isotherms by the Frontal Analysis Method. Some Identification Aspects Adsorption Science & Technology |
| title | Determination of the Parameters of Langmuir-Type Isotherms by the Frontal Analysis Method. Some Identification Aspects |
| title_full | Determination of the Parameters of Langmuir-Type Isotherms by the Frontal Analysis Method. Some Identification Aspects |
| title_fullStr | Determination of the Parameters of Langmuir-Type Isotherms by the Frontal Analysis Method. Some Identification Aspects |
| title_full_unstemmed | Determination of the Parameters of Langmuir-Type Isotherms by the Frontal Analysis Method. Some Identification Aspects |
| title_short | Determination of the Parameters of Langmuir-Type Isotherms by the Frontal Analysis Method. Some Identification Aspects |
| title_sort | determination of the parameters of langmuir type isotherms by the frontal analysis method some identification aspects |
| url | https://doi.org/10.1260/026361705775373260 |
| work_keys_str_mv | AT waldemarnowicki determinationoftheparametersoflangmuirtypeisothermsbythefrontalanalysismethodsomeidentificationaspects AT grazynanowicka determinationoftheparametersoflangmuirtypeisothermsbythefrontalanalysismethodsomeidentificationaspects |