Insights into the localized corrosion initiation mechanisms of alloy 718

Nickel alloys are widely used in the oil and gas industry where high corrosion resistance in chloride water or in sour environments is required. When high mechanical properties are required in combination with high corrosion properties, alloy 718 (UNS N07718) is one of the preferred choices, althoug...

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Main Authors: Julia Botinha, Bodo Gehrmann, Helena Alves, Michael Rohwerder
Format: Article
Language:English
Published: Elsevier 2025-01-01
Series:Heliyon
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Online Access:http://www.sciencedirect.com/science/article/pii/S2405844025001343
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author Julia Botinha
Bodo Gehrmann
Helena Alves
Michael Rohwerder
author_facet Julia Botinha
Bodo Gehrmann
Helena Alves
Michael Rohwerder
author_sort Julia Botinha
collection DOAJ
description Nickel alloys are widely used in the oil and gas industry where high corrosion resistance in chloride water or in sour environments is required. When high mechanical properties are required in combination with high corrosion properties, alloy 718 (UNS N07718) is one of the preferred choices, although it still presents limitations in terms of corrosion resistance in some applications: despite offering outstanding resistance to localized corrosion, alloy 718 is not immune to it. Its high corrosion resistance is mainly due to its high nickel and chromium contents combined with additions of molybdenum and other noble elements. Metallic and non-metallic precipitates are formed during the manufacturing process and each is known to interact with the matrix and the oxide protective film, but there is a lack of studies on the mechanisms that occur during the initiation of localized corrosion in this alloy. In this work, we investigate the localized corrosion initiation process and follow up the first steps of corrosion attack in alloy 718 in a 1M NaCl solution through the combination of microscopy and electrochemical techniques. As a result of potential application in a brine electrolyte, we conclude that nitrides and carbides play an important role on the corrosion initiation.
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publishDate 2025-01-01
publisher Elsevier
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series Heliyon
spelling doaj-art-a0f2a0e71b4d4173bf0309f68233ed142025-02-02T05:28:05ZengElsevierHeliyon2405-84402025-01-01112e41754Insights into the localized corrosion initiation mechanisms of alloy 718Julia Botinha0Bodo Gehrmann1Helena Alves2Michael Rohwerder3VDM Metals International GmbH, Kleffstraße 23, 58762, Altena, Germany; Corresponding author.VDM Metals International GmbH, Kleffstraße 23, 58762, Altena, GermanyVDM Metals International GmbH, Kleffstraße 23, 58762, Altena, GermanyMax Planck Institute for Sustainable Materials, Max-Planck-Straße 1, 40237, Düsseldorf, GermanyNickel alloys are widely used in the oil and gas industry where high corrosion resistance in chloride water or in sour environments is required. When high mechanical properties are required in combination with high corrosion properties, alloy 718 (UNS N07718) is one of the preferred choices, although it still presents limitations in terms of corrosion resistance in some applications: despite offering outstanding resistance to localized corrosion, alloy 718 is not immune to it. Its high corrosion resistance is mainly due to its high nickel and chromium contents combined with additions of molybdenum and other noble elements. Metallic and non-metallic precipitates are formed during the manufacturing process and each is known to interact with the matrix and the oxide protective film, but there is a lack of studies on the mechanisms that occur during the initiation of localized corrosion in this alloy. In this work, we investigate the localized corrosion initiation process and follow up the first steps of corrosion attack in alloy 718 in a 1M NaCl solution through the combination of microscopy and electrochemical techniques. As a result of potential application in a brine electrolyte, we conclude that nitrides and carbides play an important role on the corrosion initiation.http://www.sciencedirect.com/science/article/pii/S2405844025001343Nickel based-alloyPolarizationSEMInclusionInterfacesPitting corrosion
spellingShingle Julia Botinha
Bodo Gehrmann
Helena Alves
Michael Rohwerder
Insights into the localized corrosion initiation mechanisms of alloy 718
Heliyon
Nickel based-alloy
Polarization
SEM
Inclusion
Interfaces
Pitting corrosion
title Insights into the localized corrosion initiation mechanisms of alloy 718
title_full Insights into the localized corrosion initiation mechanisms of alloy 718
title_fullStr Insights into the localized corrosion initiation mechanisms of alloy 718
title_full_unstemmed Insights into the localized corrosion initiation mechanisms of alloy 718
title_short Insights into the localized corrosion initiation mechanisms of alloy 718
title_sort insights into the localized corrosion initiation mechanisms of alloy 718
topic Nickel based-alloy
Polarization
SEM
Inclusion
Interfaces
Pitting corrosion
url http://www.sciencedirect.com/science/article/pii/S2405844025001343
work_keys_str_mv AT juliabotinha insightsintothelocalizedcorrosioninitiationmechanismsofalloy718
AT bodogehrmann insightsintothelocalizedcorrosioninitiationmechanismsofalloy718
AT helenaalves insightsintothelocalizedcorrosioninitiationmechanismsofalloy718
AT michaelrohwerder insightsintothelocalizedcorrosioninitiationmechanismsofalloy718