Preparation

Some hexanamide-mono and di-linoleniate esters were prepared by the reaction of linolenic acid and hexanamide (derived from the reaction of hexanoic acid and diethanolamine). The chemical structure for the newly prepared hexanamide-mono and di-linoleniate esters were elucidated using elemental analy...

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Bibliographic Details
Main Authors: M.M. Dardir, S. Ibrahime, M. Soliman, S.D. Desouky, A.A. Hafiz
Format: Article
Language:English
Published: Egyptian Petroleum Research Institute 2014-03-01
Series:Egyptian Journal of Petroleum
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Online Access:http://www.sciencedirect.com/science/article/pii/S1110062114000087
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Summary:Some hexanamide-mono and di-linoleniate esters were prepared by the reaction of linolenic acid and hexanamide (derived from the reaction of hexanoic acid and diethanolamine). The chemical structure for the newly prepared hexanamide-mono and di-linoleniate esters were elucidated using elemental analysis, (FTIR), H 1NMR and chemical ionization mass spectra (CI/Ms) spectroscopic techniques. The results of the spectroscopic analysis indicated that they were prepared through the right method and they have high purity. The new prepared esters have high biodegradability and lower toxicity (environmentally friendly) so they were evaluated as a synthetic-based mud (ester-based mud) for oil-well drilling fluids. The evaluation included study of the rheological properties, filtration and thermal properties of the ester based-muds formulated with the newly prepared esters compared to the reference commercial synthetic-based mud.
ISSN:1110-0621