Catalytic β-Bromohydroxylation of Natural Terpenes: Useful Intermediates for the Synthesis of Terpenic Epoxides
In a one-step procedure, various β-bromoalcohols were synthesized from natural terpenes in good to excellent yields. Using different catalysts, the reaction was carried out at room temperature, with H2O as nucleophile and N-bromosuccinimide as a bromine source under mild reaction conditions. The syn...
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| Main Authors: | , , , , , |
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| Format: | Article |
| Language: | English |
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Wiley
2019-01-01
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| Series: | Journal of Chemistry |
| Online Access: | http://dx.doi.org/10.1155/2019/9268567 |
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| author | Saadia Oubaassine Angela Köckritz Reinhard Eckelt Andreas Martin Mustapha Ait Ali Larbi El Firdoussi |
| author_facet | Saadia Oubaassine Angela Köckritz Reinhard Eckelt Andreas Martin Mustapha Ait Ali Larbi El Firdoussi |
| author_sort | Saadia Oubaassine |
| collection | DOAJ |
| description | In a one-step procedure, various β-bromoalcohols were synthesized from natural terpenes in good to excellent yields. Using different catalysts, the reaction was carried out at room temperature, with H2O as nucleophile and N-bromosuccinimide as a bromine source under mild reaction conditions. The synthesized β-bromoalcohols were subsequently converted in situ to the corresponding epoxides in good yields. |
| format | Article |
| id | doaj-art-9fbd98611faf4fa0a3a858bc263c46e1 |
| institution | Kabale University |
| issn | 2090-9063 2090-9071 |
| language | English |
| publishDate | 2019-01-01 |
| publisher | Wiley |
| record_format | Article |
| series | Journal of Chemistry |
| spelling | doaj-art-9fbd98611faf4fa0a3a858bc263c46e12025-02-03T05:59:51ZengWileyJournal of Chemistry2090-90632090-90712019-01-01201910.1155/2019/92685679268567Catalytic β-Bromohydroxylation of Natural Terpenes: Useful Intermediates for the Synthesis of Terpenic EpoxidesSaadia Oubaassine0Angela Köckritz1Reinhard Eckelt2Andreas Martin3Mustapha Ait Ali4Larbi El Firdoussi5Leibniz-Institut für Katalyse e. V. (LIKAT Rostock), Albert-Einstein-Str. 29 a, 18059 Rostock, GermanyLeibniz-Institut für Katalyse e. V. (LIKAT Rostock), Albert-Einstein-Str. 29 a, 18059 Rostock, GermanyLeibniz-Institut für Katalyse e. V. (LIKAT Rostock), Albert-Einstein-Str. 29 a, 18059 Rostock, GermanyLeibniz-Institut für Katalyse e. V. (LIKAT Rostock), Albert-Einstein-Str. 29 a, 18059 Rostock, GermanyDepartment of Chemistry, Equipe de Chimie de Coordination et Catalyse, Faculty of Sciences Semlalia, Cadi Ayyad University, P.O. Box: 2390, 40001 Marrakech, MoroccoDepartment of Chemistry, Equipe de Chimie de Coordination et Catalyse, Faculty of Sciences Semlalia, Cadi Ayyad University, P.O. Box: 2390, 40001 Marrakech, MoroccoIn a one-step procedure, various β-bromoalcohols were synthesized from natural terpenes in good to excellent yields. Using different catalysts, the reaction was carried out at room temperature, with H2O as nucleophile and N-bromosuccinimide as a bromine source under mild reaction conditions. The synthesized β-bromoalcohols were subsequently converted in situ to the corresponding epoxides in good yields.http://dx.doi.org/10.1155/2019/9268567 |
| spellingShingle | Saadia Oubaassine Angela Köckritz Reinhard Eckelt Andreas Martin Mustapha Ait Ali Larbi El Firdoussi Catalytic β-Bromohydroxylation of Natural Terpenes: Useful Intermediates for the Synthesis of Terpenic Epoxides Journal of Chemistry |
| title | Catalytic β-Bromohydroxylation of Natural Terpenes: Useful Intermediates for the Synthesis of Terpenic Epoxides |
| title_full | Catalytic β-Bromohydroxylation of Natural Terpenes: Useful Intermediates for the Synthesis of Terpenic Epoxides |
| title_fullStr | Catalytic β-Bromohydroxylation of Natural Terpenes: Useful Intermediates for the Synthesis of Terpenic Epoxides |
| title_full_unstemmed | Catalytic β-Bromohydroxylation of Natural Terpenes: Useful Intermediates for the Synthesis of Terpenic Epoxides |
| title_short | Catalytic β-Bromohydroxylation of Natural Terpenes: Useful Intermediates for the Synthesis of Terpenic Epoxides |
| title_sort | catalytic β bromohydroxylation of natural terpenes useful intermediates for the synthesis of terpenic epoxides |
| url | http://dx.doi.org/10.1155/2019/9268567 |
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