Compositional Variation of PCBs, PAHs, and OCPs at Gas Phase and Size Segregated Particle Phase during Dust Incursion from the Saharan Desert in the Northwestern Anatolian Peninsula

A dust incursion occurred in Istanbul on 1 February 2015 from the Saharan Desert. During this episode, 938 μg·m−3 of TSP concentration was observed. TSP concentration was 64 μg·m−3 and 78 μg·m−3 on the following two days. Particles of 3 μm were dominant during the episode; however, particles < 0....

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Main Author: S. Levent Kuzu
Format: Article
Language:English
Published: Wiley 2016-01-01
Series:Advances in Meteorology
Online Access:http://dx.doi.org/10.1155/2016/7153286
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author S. Levent Kuzu
author_facet S. Levent Kuzu
author_sort S. Levent Kuzu
collection DOAJ
description A dust incursion occurred in Istanbul on 1 February 2015 from the Saharan Desert. During this episode, 938 μg·m−3 of TSP concentration was observed. TSP concentration was 64 μg·m−3 and 78 μg·m−3 on the following two days. Particles of 3 μm were dominant during the episode; however, particles < 0.49 μm were dominant after the episode. The averages of total (gas + particle) PCB, PAH, and OCP concentrations were 279 pg·m−3, 175 ng·m−3, and 589 pg·m−3, respectively. Tri-CBs were dominant in most of the samples. Flt and Phe had the highest contribution to PAH species. β-HCH and heptachlor had the highest share in terms of OCPs. Particle phase PCBs exhibited monomodal size distribution, whereas OCPs had bimodal size distribution. PAHs exhibited either monomodal or bimodal size distribution on different days. The mass median diameter of PAHs did not change significantly during different atmospheric conditions due to their local sources. Gas/particle partitioning of each pollutant was evaluated by plotting their subcooled vapor pressure against the partitioning coefficient. From 1 to 3 February, the slope of the regression line shifted close to −1, indicating that the least favorable conditions were present during dust incursion for an equilibrium state.
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spelling doaj-art-9c58b014128242e1afc73a01ebf6ceb62025-02-03T06:44:44ZengWileyAdvances in Meteorology1687-93091687-93172016-01-01201610.1155/2016/71532867153286Compositional Variation of PCBs, PAHs, and OCPs at Gas Phase and Size Segregated Particle Phase during Dust Incursion from the Saharan Desert in the Northwestern Anatolian PeninsulaS. Levent Kuzu0Environmental Engineering Department, Civil Engineering Faculty, Yildiz Technical University, Davutpaşa, Esenler, 34220 Istanbul, TurkeyA dust incursion occurred in Istanbul on 1 February 2015 from the Saharan Desert. During this episode, 938 μg·m−3 of TSP concentration was observed. TSP concentration was 64 μg·m−3 and 78 μg·m−3 on the following two days. Particles of 3 μm were dominant during the episode; however, particles < 0.49 μm were dominant after the episode. The averages of total (gas + particle) PCB, PAH, and OCP concentrations were 279 pg·m−3, 175 ng·m−3, and 589 pg·m−3, respectively. Tri-CBs were dominant in most of the samples. Flt and Phe had the highest contribution to PAH species. β-HCH and heptachlor had the highest share in terms of OCPs. Particle phase PCBs exhibited monomodal size distribution, whereas OCPs had bimodal size distribution. PAHs exhibited either monomodal or bimodal size distribution on different days. The mass median diameter of PAHs did not change significantly during different atmospheric conditions due to their local sources. Gas/particle partitioning of each pollutant was evaluated by plotting their subcooled vapor pressure against the partitioning coefficient. From 1 to 3 February, the slope of the regression line shifted close to −1, indicating that the least favorable conditions were present during dust incursion for an equilibrium state.http://dx.doi.org/10.1155/2016/7153286
spellingShingle S. Levent Kuzu
Compositional Variation of PCBs, PAHs, and OCPs at Gas Phase and Size Segregated Particle Phase during Dust Incursion from the Saharan Desert in the Northwestern Anatolian Peninsula
Advances in Meteorology
title Compositional Variation of PCBs, PAHs, and OCPs at Gas Phase and Size Segregated Particle Phase during Dust Incursion from the Saharan Desert in the Northwestern Anatolian Peninsula
title_full Compositional Variation of PCBs, PAHs, and OCPs at Gas Phase and Size Segregated Particle Phase during Dust Incursion from the Saharan Desert in the Northwestern Anatolian Peninsula
title_fullStr Compositional Variation of PCBs, PAHs, and OCPs at Gas Phase and Size Segregated Particle Phase during Dust Incursion from the Saharan Desert in the Northwestern Anatolian Peninsula
title_full_unstemmed Compositional Variation of PCBs, PAHs, and OCPs at Gas Phase and Size Segregated Particle Phase during Dust Incursion from the Saharan Desert in the Northwestern Anatolian Peninsula
title_short Compositional Variation of PCBs, PAHs, and OCPs at Gas Phase and Size Segregated Particle Phase during Dust Incursion from the Saharan Desert in the Northwestern Anatolian Peninsula
title_sort compositional variation of pcbs pahs and ocps at gas phase and size segregated particle phase during dust incursion from the saharan desert in the northwestern anatolian peninsula
url http://dx.doi.org/10.1155/2016/7153286
work_keys_str_mv AT sleventkuzu compositionalvariationofpcbspahsandocpsatgasphaseandsizesegregatedparticlephaseduringdustincursionfromthesaharandesertinthenorthwesternanatolianpeninsula