NHCs Catalyzed Hydrophosphonylation of α-Ketoesters and α-Trifluoromethyl Ketones
N-Heterocyclic carbenes catalyzed hydrophosphonylation reaction of α-ketoesters and α-trifluoromethyl ketones was developed. Under the catalysis of 10 mol% IPr, α-ketoesters or α-trifluoromethyl ketones reacted with dialkyl phosphites to provide quaternary α-hydroxyphosphonates in good to excellent...
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| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
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Wiley
2013-01-01
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| Series: | The Scientific World Journal |
| Online Access: | http://dx.doi.org/10.1155/2013/890187 |
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| _version_ | 1832568304407937024 |
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| author | Lin He Zhi-Hua Cai Ji-Xin Pian Guang-Fen Du |
| author_facet | Lin He Zhi-Hua Cai Ji-Xin Pian Guang-Fen Du |
| author_sort | Lin He |
| collection | DOAJ |
| description | N-Heterocyclic carbenes catalyzed hydrophosphonylation reaction of α-ketoesters and α-trifluoromethyl ketones was developed. Under the catalysis of 10 mol% IPr, α-ketoesters or α-trifluoromethyl ketones reacted with dialkyl phosphites to provide quaternary α-hydroxyphosphonates in good to excellent yield. |
| format | Article |
| id | doaj-art-9849a5ecc8d64442bd7a56384928bab9 |
| institution | Kabale University |
| issn | 1537-744X |
| language | English |
| publishDate | 2013-01-01 |
| publisher | Wiley |
| record_format | Article |
| series | The Scientific World Journal |
| spelling | doaj-art-9849a5ecc8d64442bd7a56384928bab92025-02-03T00:59:24ZengWileyThe Scientific World Journal1537-744X2013-01-01201310.1155/2013/890187890187NHCs Catalyzed Hydrophosphonylation of α-Ketoesters and α-Trifluoromethyl KetonesLin He0Zhi-Hua Cai1Ji-Xin Pian2Guang-Fen Du3Key Laboratory for Green Processing of Chemical Engineering of Xinjiang Bingtuan and School of Chemistry and Chemical Engineering, Shihezi University, Xinjiang 832000, ChinaKey Laboratory for Green Processing of Chemical Engineering of Xinjiang Bingtuan and School of Chemistry and Chemical Engineering, Shihezi University, Xinjiang 832000, ChinaKey Laboratory for Green Processing of Chemical Engineering of Xinjiang Bingtuan and School of Chemistry and Chemical Engineering, Shihezi University, Xinjiang 832000, ChinaKey Laboratory for Green Processing of Chemical Engineering of Xinjiang Bingtuan and School of Chemistry and Chemical Engineering, Shihezi University, Xinjiang 832000, ChinaN-Heterocyclic carbenes catalyzed hydrophosphonylation reaction of α-ketoesters and α-trifluoromethyl ketones was developed. Under the catalysis of 10 mol% IPr, α-ketoesters or α-trifluoromethyl ketones reacted with dialkyl phosphites to provide quaternary α-hydroxyphosphonates in good to excellent yield.http://dx.doi.org/10.1155/2013/890187 |
| spellingShingle | Lin He Zhi-Hua Cai Ji-Xin Pian Guang-Fen Du NHCs Catalyzed Hydrophosphonylation of α-Ketoesters and α-Trifluoromethyl Ketones The Scientific World Journal |
| title | NHCs Catalyzed Hydrophosphonylation of α-Ketoesters and α-Trifluoromethyl Ketones |
| title_full | NHCs Catalyzed Hydrophosphonylation of α-Ketoesters and α-Trifluoromethyl Ketones |
| title_fullStr | NHCs Catalyzed Hydrophosphonylation of α-Ketoesters and α-Trifluoromethyl Ketones |
| title_full_unstemmed | NHCs Catalyzed Hydrophosphonylation of α-Ketoesters and α-Trifluoromethyl Ketones |
| title_short | NHCs Catalyzed Hydrophosphonylation of α-Ketoesters and α-Trifluoromethyl Ketones |
| title_sort | nhcs catalyzed hydrophosphonylation of α ketoesters and α trifluoromethyl ketones |
| url | http://dx.doi.org/10.1155/2013/890187 |
| work_keys_str_mv | AT linhe nhcscatalyzedhydrophosphonylationofaketoestersandatrifluoromethylketones AT zhihuacai nhcscatalyzedhydrophosphonylationofaketoestersandatrifluoromethylketones AT jixinpian nhcscatalyzedhydrophosphonylationofaketoestersandatrifluoromethylketones AT guangfendu nhcscatalyzedhydrophosphonylationofaketoestersandatrifluoromethylketones |