1,2-Di-tert-butylmethylenphosphan und seine Addukte mit Aluminiumtrichlorid, Schwefel und Selen

Synthesis and spectroscopic data of a novel phosphaalkene, R–P=CH–R (2:R = C(CH3)3), are reported. With AlCl3 this phosphaalkene reacts to the Lewis acidbase adduct 7, while with sulfur and selenium it reacts to the three-membered ring compounds 8 and 9, respectively, via a nucleophilic attack at t...

Full description

Saved in:
Bibliographic Details
Main Authors: Edgar Niecke, Erhard Symalla
Format: Article
Language:deu
Published: Swiss Chemical Society 1985-10-01
Series:CHIMIA
Online Access:https://www.chimia.ch/chimia/article/view/9691
Tags: Add Tag
No Tags, Be the first to tag this record!