Synthesis, Crystal Structure Refinement, and Electrical Conductivity of Pb(8−x)Na2Smx(VO4)6O(x/2)
Solid solutions of Pb(8−x)Na2Smx(VO4)6O(x/2) were studied using X-ray diffraction analysis including Rietveld refinement and scanning electron microscopy and by measuring their electrical conductivity. Crystal structure of the solid solutions was refined and the solubility region 0≤x≤0.2 was determi...
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| Format: | Article |
| Language: | English |
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Wiley
2014-01-01
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| Series: | Journal of Chemistry |
| Online Access: | http://dx.doi.org/10.1155/2014/263548 |
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| author | Tatiana M. Savankova Lev G. Akselrud Lyudmyla I. Ardanova Alexey V. Ignatov Eugeni I. Get’man Roman E. Gladyshevskii Stanislav N. Loboda |
| author_facet | Tatiana M. Savankova Lev G. Akselrud Lyudmyla I. Ardanova Alexey V. Ignatov Eugeni I. Get’man Roman E. Gladyshevskii Stanislav N. Loboda |
| author_sort | Tatiana M. Savankova |
| collection | DOAJ |
| description | Solid solutions of Pb(8−x)Na2Smx(VO4)6O(x/2) were studied using X-ray diffraction analysis including Rietveld refinement and scanning electron microscopy and by measuring their electrical conductivity. Crystal structure of the solid solutions was refined and the solubility region 0≤x≤0.2 was determined for samarium substitution for lead under the scheme 2Pb2++□→2Sm3++O2-. The influence of degree of substitution on the electrical conductivity of solid solutions was established. |
| format | Article |
| id | doaj-art-8dd4868e5e8b4d6f93325e3d59de2534 |
| institution | Kabale University |
| issn | 2090-9063 2090-9071 |
| language | English |
| publishDate | 2014-01-01 |
| publisher | Wiley |
| record_format | Article |
| series | Journal of Chemistry |
| spelling | doaj-art-8dd4868e5e8b4d6f93325e3d59de25342025-02-03T01:27:13ZengWileyJournal of Chemistry2090-90632090-90712014-01-01201410.1155/2014/263548263548Synthesis, Crystal Structure Refinement, and Electrical Conductivity of Pb(8−x)Na2Smx(VO4)6O(x/2)Tatiana M. Savankova0Lev G. Akselrud1Lyudmyla I. Ardanova2Alexey V. Ignatov3Eugeni I. Get’man4Roman E. Gladyshevskii5Stanislav N. Loboda6Department of Inorganic Chemistry, Donetsk National University, 24 Universitetskaya, Donetsk 83001, UkraineDepartment of Inorganic Chemistry, Ivan Franko National University of Lviv, 6 Kyryla i Mephodiya Street, Lviv 79005, UkraineDepartment of Chemistry and Geology, Minnesota State University, 241 Ford Hall, Mankato, MN 56001, USADepartment of Inorganic Chemistry, Donetsk National University, 24 Universitetskaya, Donetsk 83001, UkraineDepartment of Inorganic Chemistry, Donetsk National University, 24 Universitetskaya, Donetsk 83001, UkraineDepartment of Inorganic Chemistry, Ivan Franko National University of Lviv, 6 Kyryla i Mephodiya Street, Lviv 79005, UkraineDepartment of Inorganic Chemistry, Donetsk National University, 24 Universitetskaya, Donetsk 83001, UkraineSolid solutions of Pb(8−x)Na2Smx(VO4)6O(x/2) were studied using X-ray diffraction analysis including Rietveld refinement and scanning electron microscopy and by measuring their electrical conductivity. Crystal structure of the solid solutions was refined and the solubility region 0≤x≤0.2 was determined for samarium substitution for lead under the scheme 2Pb2++□→2Sm3++O2-. The influence of degree of substitution on the electrical conductivity of solid solutions was established.http://dx.doi.org/10.1155/2014/263548 |
| spellingShingle | Tatiana M. Savankova Lev G. Akselrud Lyudmyla I. Ardanova Alexey V. Ignatov Eugeni I. Get’man Roman E. Gladyshevskii Stanislav N. Loboda Synthesis, Crystal Structure Refinement, and Electrical Conductivity of Pb(8−x)Na2Smx(VO4)6O(x/2) Journal of Chemistry |
| title | Synthesis, Crystal Structure Refinement, and Electrical Conductivity of Pb(8−x)Na2Smx(VO4)6O(x/2) |
| title_full | Synthesis, Crystal Structure Refinement, and Electrical Conductivity of Pb(8−x)Na2Smx(VO4)6O(x/2) |
| title_fullStr | Synthesis, Crystal Structure Refinement, and Electrical Conductivity of Pb(8−x)Na2Smx(VO4)6O(x/2) |
| title_full_unstemmed | Synthesis, Crystal Structure Refinement, and Electrical Conductivity of Pb(8−x)Na2Smx(VO4)6O(x/2) |
| title_short | Synthesis, Crystal Structure Refinement, and Electrical Conductivity of Pb(8−x)Na2Smx(VO4)6O(x/2) |
| title_sort | synthesis crystal structure refinement and electrical conductivity of pb 8 x na2smx vo4 6o x 2 |
| url | http://dx.doi.org/10.1155/2014/263548 |
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