Structural and Phase Transformations in Water-Vapour-Plasma-Treated Hydrophilic TiO2 Films

We have investigated structural and phase transformations in water-vapor-plasma-treated 200–300 nm thick Ti films, maintained at room temperature, by injecting water vapor into radio frequency (RF) plasma at different processing powers. Scanning electron microscopy (SEM) combined with optical micros...

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Main Authors: L. Pranevicius, M. Urbonavicius, S. Tuckute, K. Gedvilas, T. Rajackas, L. L. Pranevicius, D. Milcius
Format: Article
Language:English
Published: Wiley 2012-01-01
Series:Advances in Materials Science and Engineering
Online Access:http://dx.doi.org/10.1155/2012/592485
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author L. Pranevicius
M. Urbonavicius
S. Tuckute
K. Gedvilas
T. Rajackas
L. L. Pranevicius
D. Milcius
author_facet L. Pranevicius
M. Urbonavicius
S. Tuckute
K. Gedvilas
T. Rajackas
L. L. Pranevicius
D. Milcius
author_sort L. Pranevicius
collection DOAJ
description We have investigated structural and phase transformations in water-vapor-plasma-treated 200–300 nm thick Ti films, maintained at room temperature, by injecting water vapor into radio frequency (RF) plasma at different processing powers. Scanning electron microscopy (SEM) combined with optical microscopy and surface nanotopography analysis were used to view tracks of adsorbed water layers and to detect bulges or blisters appeared on the surface of treated samples. Rough surfaces with different size of holes (5–20 μm) through the entire film thickness have been observed. X-ray diffraction results show that the oxidation rate of Ti film drastically increases in the presence of an adsorbed water on the hydrophilic layer. It is assumed that the defining factor which controls oxidation kinetics is the hydroxyl radicals formation.
format Article
id doaj-art-8ac67f3f21e64f868b889ebcea5fc42c
institution Kabale University
issn 1687-8434
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language English
publishDate 2012-01-01
publisher Wiley
record_format Article
series Advances in Materials Science and Engineering
spelling doaj-art-8ac67f3f21e64f868b889ebcea5fc42c2025-02-03T05:48:16ZengWileyAdvances in Materials Science and Engineering1687-84341687-84422012-01-01201210.1155/2012/592485592485Structural and Phase Transformations in Water-Vapour-Plasma-Treated Hydrophilic TiO2 FilmsL. Pranevicius0M. Urbonavicius1S. Tuckute2K. Gedvilas3T. Rajackas4L. L. Pranevicius5D. Milcius6Physics Department, Vytautas Magnus University, Vileikos Street 8, 44404, Kaunas, LithuaniaPhysics Department, Vytautas Magnus University, Vileikos Street 8, 44404, Kaunas, LithuaniaPhysics Department, Vytautas Magnus University, Vileikos Street 8, 44404, Kaunas, LithuaniaPhysics Department, Vytautas Magnus University, Vileikos Street 8, 44404, Kaunas, LithuaniaPhysics Department, Vytautas Magnus University, Vileikos Street 8, 44404, Kaunas, LithuaniaPhysics Department, Vytautas Magnus University, Vileikos Street 8, 44404, Kaunas, LithuaniaPhysics Department, Vytautas Magnus University, Vileikos Street 8, 44404, Kaunas, LithuaniaWe have investigated structural and phase transformations in water-vapor-plasma-treated 200–300 nm thick Ti films, maintained at room temperature, by injecting water vapor into radio frequency (RF) plasma at different processing powers. Scanning electron microscopy (SEM) combined with optical microscopy and surface nanotopography analysis were used to view tracks of adsorbed water layers and to detect bulges or blisters appeared on the surface of treated samples. Rough surfaces with different size of holes (5–20 μm) through the entire film thickness have been observed. X-ray diffraction results show that the oxidation rate of Ti film drastically increases in the presence of an adsorbed water on the hydrophilic layer. It is assumed that the defining factor which controls oxidation kinetics is the hydroxyl radicals formation.http://dx.doi.org/10.1155/2012/592485
spellingShingle L. Pranevicius
M. Urbonavicius
S. Tuckute
K. Gedvilas
T. Rajackas
L. L. Pranevicius
D. Milcius
Structural and Phase Transformations in Water-Vapour-Plasma-Treated Hydrophilic TiO2 Films
Advances in Materials Science and Engineering
title Structural and Phase Transformations in Water-Vapour-Plasma-Treated Hydrophilic TiO2 Films
title_full Structural and Phase Transformations in Water-Vapour-Plasma-Treated Hydrophilic TiO2 Films
title_fullStr Structural and Phase Transformations in Water-Vapour-Plasma-Treated Hydrophilic TiO2 Films
title_full_unstemmed Structural and Phase Transformations in Water-Vapour-Plasma-Treated Hydrophilic TiO2 Films
title_short Structural and Phase Transformations in Water-Vapour-Plasma-Treated Hydrophilic TiO2 Films
title_sort structural and phase transformations in water vapour plasma treated hydrophilic tio2 films
url http://dx.doi.org/10.1155/2012/592485
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