The Defect Structure Evolution in MgH<sub>2</sub>-EEWNi Composites in Hydrogen Sorption–Desorption Processes
This paper presents the results of the study of the composite based on magnesium hydride with the addition of nanosized nickel powder, obtained by the method of an electric explosion of wires. The obtained MgH<sub>2</sub>-EEWNi (20 wt.%) composite with the core-shell configuration demons...
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MDPI AG
2025-01-01
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| author | Viktor N. Kudiiarov Alan Kenzhiyev Roman R. Elman Nikita Kurdyumov Ivan A. Ushakov Andrei V. Tereshchenko Roman S. Laptev Mark A. Kruglyakov Parvizi I. Khomidzoda |
| author_facet | Viktor N. Kudiiarov Alan Kenzhiyev Roman R. Elman Nikita Kurdyumov Ivan A. Ushakov Andrei V. Tereshchenko Roman S. Laptev Mark A. Kruglyakov Parvizi I. Khomidzoda |
| author_sort | Viktor N. Kudiiarov |
| collection | DOAJ |
| description | This paper presents the results of the study of the composite based on magnesium hydride with the addition of nanosized nickel powder, obtained by the method of an electric explosion of wires. The obtained MgH<sub>2</sub>-EEWNi (20 wt.%) composite with the core-shell configuration demonstrated the development of a defect structure, which makes it possible to significantly reduce the hydrogen desorption temperature from 418 °C for pure magnesium hydride to 229 °C for hydride with the addition of nickel powder. In situ studies of the evolution of the defect structure using positron annihilation methods and diffraction methods made it possible to draw conclusions about the influence of the Mg<sub>2</sub>NiH<sub>0.3</sub> and Mg<sub>2</sub>NiH<sub>4</sub> phases on the sorption and desorption properties of the composite. The results obtained in this work can be used in the field of hydrogen energy in mobile or stationary hydrogen storage systems. |
| format | Article |
| id | doaj-art-85d9e1b621b74aa3914f9ce7a68d7f38 |
| institution | Kabale University |
| issn | 2075-4701 |
| language | English |
| publishDate | 2025-01-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Metals |
| spelling | doaj-art-85d9e1b621b74aa3914f9ce7a68d7f382025-01-24T13:41:35ZengMDPI AGMetals2075-47012025-01-011517210.3390/met15010072The Defect Structure Evolution in MgH<sub>2</sub>-EEWNi Composites in Hydrogen Sorption–Desorption ProcessesViktor N. Kudiiarov0Alan Kenzhiyev1Roman R. Elman2Nikita Kurdyumov3Ivan A. Ushakov4Andrei V. Tereshchenko5Roman S. Laptev6Mark A. Kruglyakov7Parvizi I. Khomidzoda8Division for Experimental Physics, School of Nuclear Science & Engineering, National Research Tomsk Polytechnic University, 634050 Tomsk, RussiaDivision for Experimental Physics, School of Nuclear Science & Engineering, National Research Tomsk Polytechnic University, 634050 Tomsk, RussiaDivision for Experimental Physics, School of Nuclear Science & Engineering, National Research Tomsk Polytechnic University, 634050 Tomsk, RussiaDivision for Experimental Physics, School of Nuclear Science & Engineering, National Research Tomsk Polytechnic University, 634050 Tomsk, RussiaDivision for Experimental Physics, School of Nuclear Science & Engineering, National Research Tomsk Polytechnic University, 634050 Tomsk, RussiaDivision for Experimental Physics, School of Nuclear Science & Engineering, National Research Tomsk Polytechnic University, 634050 Tomsk, RussiaDivision for Experimental Physics, School of Nuclear Science & Engineering, National Research Tomsk Polytechnic University, 634050 Tomsk, RussiaDivision for Experimental Physics, School of Nuclear Science & Engineering, National Research Tomsk Polytechnic University, 634050 Tomsk, RussiaDivision for Experimental Physics, School of Nuclear Science & Engineering, National Research Tomsk Polytechnic University, 634050 Tomsk, RussiaThis paper presents the results of the study of the composite based on magnesium hydride with the addition of nanosized nickel powder, obtained by the method of an electric explosion of wires. The obtained MgH<sub>2</sub>-EEWNi (20 wt.%) composite with the core-shell configuration demonstrated the development of a defect structure, which makes it possible to significantly reduce the hydrogen desorption temperature from 418 °C for pure magnesium hydride to 229 °C for hydride with the addition of nickel powder. In situ studies of the evolution of the defect structure using positron annihilation methods and diffraction methods made it possible to draw conclusions about the influence of the Mg<sub>2</sub>NiH<sub>0.3</sub> and Mg<sub>2</sub>NiH<sub>4</sub> phases on the sorption and desorption properties of the composite. The results obtained in this work can be used in the field of hydrogen energy in mobile or stationary hydrogen storage systems.https://www.mdpi.com/2075-4701/15/1/72hydrogen storage materialmagnesium hydridenickelnanoscale powdershydrogendesorption |
| spellingShingle | Viktor N. Kudiiarov Alan Kenzhiyev Roman R. Elman Nikita Kurdyumov Ivan A. Ushakov Andrei V. Tereshchenko Roman S. Laptev Mark A. Kruglyakov Parvizi I. Khomidzoda The Defect Structure Evolution in MgH<sub>2</sub>-EEWNi Composites in Hydrogen Sorption–Desorption Processes Metals hydrogen storage material magnesium hydride nickel nanoscale powders hydrogen desorption |
| title | The Defect Structure Evolution in MgH<sub>2</sub>-EEWNi Composites in Hydrogen Sorption–Desorption Processes |
| title_full | The Defect Structure Evolution in MgH<sub>2</sub>-EEWNi Composites in Hydrogen Sorption–Desorption Processes |
| title_fullStr | The Defect Structure Evolution in MgH<sub>2</sub>-EEWNi Composites in Hydrogen Sorption–Desorption Processes |
| title_full_unstemmed | The Defect Structure Evolution in MgH<sub>2</sub>-EEWNi Composites in Hydrogen Sorption–Desorption Processes |
| title_short | The Defect Structure Evolution in MgH<sub>2</sub>-EEWNi Composites in Hydrogen Sorption–Desorption Processes |
| title_sort | defect structure evolution in mgh sub 2 sub eewni composites in hydrogen sorption desorption processes |
| topic | hydrogen storage material magnesium hydride nickel nanoscale powders hydrogen desorption |
| url | https://www.mdpi.com/2075-4701/15/1/72 |
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