C–H bond activation of benzene and thiophene by photochemically generated rhenocene cation
A cationic rhenocene-acetonitrile adduct [Cp2Re(NCMe)](BF4)(1) reacted with an excess of benzene, thiophene, 2-methylthiophene, and pyrrole under UV irradiation to afford the C–H bond activation products [Cp2Re(H)R]BF4 (R = phenyl, 2-thienyl, 2-(5-methylthienyl), 2-pyrrolyl) in high yields. In cases...
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Main Authors: | , , , |
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Format: | Article |
Language: | English |
Published: |
Wiley
1999-01-01
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Series: | International Journal of Photoenergy |
Online Access: | http://dx.doi.org/10.1155/S1110662X99000276 |
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