Mechanical and Structural Properties of Fluorine-Ion-Implanted Boron Suboxide

Results on a systematic study on the effects of ion implantation on the near-surface mechanical and structural properties of boron suboxide (B6O) prepared by uniaxial hot pressing are reviewed. 150 keV fluorine ions at fluences of up to 5.0×1016 ions/cm2 were implanted into the ultrahard ceramic mat...

Full description

Saved in:
Bibliographic Details
Main Authors: Ronald Machaka, Bonex W. Mwakikunga, Elayaperumal Manikandan, Trevor E. Derry, Iakovos Sigalas, Mathias Herrmann
Format: Article
Language:English
Published: Wiley 2012-01-01
Series:Advances in Materials Science and Engineering
Online Access:http://dx.doi.org/10.1155/2012/792973
Tags: Add Tag
No Tags, Be the first to tag this record!
_version_ 1832553556263043072
author Ronald Machaka
Bonex W. Mwakikunga
Elayaperumal Manikandan
Trevor E. Derry
Iakovos Sigalas
Mathias Herrmann
author_facet Ronald Machaka
Bonex W. Mwakikunga
Elayaperumal Manikandan
Trevor E. Derry
Iakovos Sigalas
Mathias Herrmann
author_sort Ronald Machaka
collection DOAJ
description Results on a systematic study on the effects of ion implantation on the near-surface mechanical and structural properties of boron suboxide (B6O) prepared by uniaxial hot pressing are reviewed. 150 keV fluorine ions at fluences of up to 5.0×1016 ions/cm2 were implanted into the ultrahard ceramic material at room temperature and characterized using Raman spectroscopy, atomic force microscopy, and scanning electron microscopy with energy-dispersive X-ray spectroscopy. Evidence of ion-beam-assisted nucleation of novel clustered BxOyFz particles by ion implantation is revealed. In addition, obtained results also reveal that fluorine implantation into the B6O specimen leads to an overall degradation of near-surface mechanical properties with increasing fluorine fluence. Implications of these observations in the creation of amorphous near-surface layers by high-dose ion implantation are discussed in this paper.
format Article
id doaj-art-84a5526349424d00b6f13d5fae8e62a8
institution Kabale University
issn 1687-8434
1687-8442
language English
publishDate 2012-01-01
publisher Wiley
record_format Article
series Advances in Materials Science and Engineering
spelling doaj-art-84a5526349424d00b6f13d5fae8e62a82025-02-03T05:53:44ZengWileyAdvances in Materials Science and Engineering1687-84341687-84422012-01-01201210.1155/2012/792973792973Mechanical and Structural Properties of Fluorine-Ion-Implanted Boron SuboxideRonald Machaka0Bonex W. Mwakikunga1Elayaperumal Manikandan2Trevor E. Derry3Iakovos Sigalas4Mathias Herrmann5DST/NRF Centre of Excellence in Strong Materials, University of the Witwatersrand, Private Bag 3, Wits, Johannesburg 2050, South AfricaNational Centre for Nano-Structured Materials, CSIR, P.O. Box 395, Pretoria 0001, South AfricaNational Centre for Nano-Structured Materials, CSIR, P.O. Box 395, Pretoria 0001, South AfricaDST/NRF Centre of Excellence in Strong Materials, University of the Witwatersrand, Private Bag 3, Wits, Johannesburg 2050, South AfricaDST/NRF Centre of Excellence in Strong Materials, University of the Witwatersrand, Private Bag 3, Wits, Johannesburg 2050, South AfricaFraunhofer Institute for Ceramic Technologies and Systems, Winterbergstraβe 28, 01277 Dresden, GermanyResults on a systematic study on the effects of ion implantation on the near-surface mechanical and structural properties of boron suboxide (B6O) prepared by uniaxial hot pressing are reviewed. 150 keV fluorine ions at fluences of up to 5.0×1016 ions/cm2 were implanted into the ultrahard ceramic material at room temperature and characterized using Raman spectroscopy, atomic force microscopy, and scanning electron microscopy with energy-dispersive X-ray spectroscopy. Evidence of ion-beam-assisted nucleation of novel clustered BxOyFz particles by ion implantation is revealed. In addition, obtained results also reveal that fluorine implantation into the B6O specimen leads to an overall degradation of near-surface mechanical properties with increasing fluorine fluence. Implications of these observations in the creation of amorphous near-surface layers by high-dose ion implantation are discussed in this paper.http://dx.doi.org/10.1155/2012/792973
spellingShingle Ronald Machaka
Bonex W. Mwakikunga
Elayaperumal Manikandan
Trevor E. Derry
Iakovos Sigalas
Mathias Herrmann
Mechanical and Structural Properties of Fluorine-Ion-Implanted Boron Suboxide
Advances in Materials Science and Engineering
title Mechanical and Structural Properties of Fluorine-Ion-Implanted Boron Suboxide
title_full Mechanical and Structural Properties of Fluorine-Ion-Implanted Boron Suboxide
title_fullStr Mechanical and Structural Properties of Fluorine-Ion-Implanted Boron Suboxide
title_full_unstemmed Mechanical and Structural Properties of Fluorine-Ion-Implanted Boron Suboxide
title_short Mechanical and Structural Properties of Fluorine-Ion-Implanted Boron Suboxide
title_sort mechanical and structural properties of fluorine ion implanted boron suboxide
url http://dx.doi.org/10.1155/2012/792973
work_keys_str_mv AT ronaldmachaka mechanicalandstructuralpropertiesoffluorineionimplantedboronsuboxide
AT bonexwmwakikunga mechanicalandstructuralpropertiesoffluorineionimplantedboronsuboxide
AT elayaperumalmanikandan mechanicalandstructuralpropertiesoffluorineionimplantedboronsuboxide
AT trevorederry mechanicalandstructuralpropertiesoffluorineionimplantedboronsuboxide
AT iakovossigalas mechanicalandstructuralpropertiesoffluorineionimplantedboronsuboxide
AT mathiasherrmann mechanicalandstructuralpropertiesoffluorineionimplantedboronsuboxide